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Physico — Chemical Properties of Supercritical Fluids

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Analytical Supercritical Fluid Extraction

Abstract

A supercritical fluid (SF) is a state where matter is compressible and behaves as a gas (i.e. it fills and takes the shape of its container), which is not the case when it is in a liquid state (an incompressible fluid that occupies the bottom of its container). However, a supercritical fluid has the typical density of a liquid (between 0.1 and l.0g/ml) and hence its characteristic dissolving power. Finally, an SF can also be defined as a heavy gas with a controllable dissolving power or as a form of matter in which the liquid and gaseous state are indistinguishable.

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References

  1. Berry RS, Rice SA, Ross J (1980) Phase equilibria in one-component systems. In: Physical chemistry. John Wiley

    Google Scholar 

  2. Shaw RW, Brill TB, Clifford AA, Eckert CA, Franck EU (1991) Supercritical water. A medium for chemistry. C&EN Special Report, pp. 23–26

    Google Scholar 

  3. Engelhardt H, Gross A (1991) Trends Anal. Chem. 10:64

    Article  CAS  Google Scholar 

  4. McHugh M, Krukonis V (1986) Supercritical fluid extraction. Principles and practice. Butterworth, Stoneham, MA

    Google Scholar 

  5. Smith RD, Frye SL, Yonker CR, Gale RW (1987) J. Phys. Chem. 91:3059

    Article  CAS  Google Scholar 

  6. Pitzer KS (1955) J. Am. Chem. Soc. 77:3427

    Article  CAS  Google Scholar 

  7. Pitzer KS, Lippman DZ, Curl RF, Huggins CM Jr, Petersen DE (1955) J. Am. Chem. Soc. 77:3433

    Article  CAS  Google Scholar 

  8. Langenfeld JJ, Hawthorne SB, Miller DJ, Tehrani J (1992) Anal. Chem. 64:2263

    Article  CAS  Google Scholar 

  9. Supercritical fluid extraction and chromatography. Techniques and applications, Charpentier BA, Sevenants MR (eds). ACS Symposium Series 366, p. 130

    Google Scholar 

  10. Schneider GM, Stahl E, Wilke G (eds) Extraction with supercritical gases. Verlag Chemie, Weinheim, p. 73

    Google Scholar 

  11. Bruno TJ, Ely JF (1991) Supercritical fluid technology. Reviews in modern theory and applications. CRC Press

    Google Scholar 

  12. van Konynenburg PH, Scott RL (1980) Critical lines and phase equilibria in binary van der waals mixtures. Philos. Trans. Royal Soc. London 298:495

    Google Scholar 

  13. Schneider GM (1978) High-pressure phase diagrams and critical properties of fluid mixtures. In: Chemical thermodynamics, Vol. 2, Specialist periodical reports. The Chemical Society, London, 105

    Chapter  Google Scholar 

  14. McHugh MA, Seckner AJ, Yogan TJ (1984) Ind. Eng. Chem. Fundam. 23:493

    Article  CAS  Google Scholar 

  15. Rowlinson JS, Richardson MJ (1959) Adv. Chem. Phys. 2:85

    Article  CAS  Google Scholar 

  16. Tehrani J, Myer L (1992) Supercritical fluid extraction method optimization using novel computer software. Pittcon’92, New Orleans

    Google Scholar 

  17. Reid RC, Prausnitz JM, Poling BE (1987) The properties of gases and liquids, 4th ed. McGraw-Hill Book Co. New York

    Google Scholar 

  18. Kamlet MJ, Abboud JL, Taft RW (1977) J. Am. Chem. Soc. 99:6027

    Article  CAS  Google Scholar 

  19. Kamlet MJ, Abboud JL, Abraham MH, Taft RW (1983) J. Org. Chem. 48:2877

    Article  CAS  Google Scholar 

  20. Sadek PC, Carr PW, Doherty RM, Kamlet MJ, Taft RW, Abraham MH (1985) Anal. Chem. 57:2971

    Article  CAS  Google Scholar 

  21. Kim S, Johnston KP (1986) Effects of supercritical solvents on the rates of homogeneous chemical reactions. ACS Symp. Ser. 329:42

    Article  Google Scholar 

  22. Smith RD, Wright BW, Yonker CR (1988) Anal. Chem. 60:1323A

    Article  CAS  Google Scholar 

  23. Langenfeld JJ, Hawthorne SB, Miller DJ, Paschke T (1992) Comparison of fluids in supercritical fluid extraction (SFE). Pittcon’92, New Orleans

    Google Scholar 

  24. Ashraf-Khorassani M, Taylor LT, Zimmermann P (1990) Anal. Chem. 62:1177

    Article  CAS  Google Scholar 

  25. Li SFY, Ong CP, Lee ML, Lee HK (1990) J. Chromatogr. 515:515

    Article  CAS  Google Scholar 

  26. Huppert GL, Wu BC, Townsend SH, Klein MT, Paspek SC (1988) Hydrolysis in supercritical water identification and implications of a polar transition state. Ing. Eng. Chem. Res. 27:143

    Article  Google Scholar 

  27. Larson KA, King ML (1986) Biotechnol. Prog. 2:73

    Article  CAS  Google Scholar 

  28. Houser TJ, Tiffany DM, Li Z, McCarville ME, Houghton ME (1986) Fuel 65:827

    Article  CAS  Google Scholar 

  29. Butler LG (1979) Enzyme Microb. Technol. 1:253

    Article  CAS  Google Scholar 

  30. Zaks A, Klibanov AM (1984) Science 224:1249

    Article  CAS  Google Scholar 

  31. Taniguchi M, Kamihira M, Kobayashi T (1987) Agric. Biol. Chem. 51:593

    Article  CAS  Google Scholar 

  32. Randolph TW, Blanch HW, Prausnitz JM, Wilke CR (1985) Biotechnol. Lett. 7:325

    Article  CAS  Google Scholar 

  33. Hammond DA, Karel M, Klibanov AM, Krukonis VJ (1985) Appl. Biochem. Biotechnol. 11:393

    Article  CAS  Google Scholar 

  34. Scholsky KM (1987) Chemtech, 750

    Google Scholar 

  35. Capriel P, Haisch A, Khan SU (1986) J. Agric. Food Chem. 34:70

    Article  CAS  Google Scholar 

  36. Hoyer GG (1985) Chemtech, 440

    Google Scholar 

  37. Hutchinson KW, Roebers JR, Thies MC (1991) Carbon 29:215

    Article  Google Scholar 

  38. Hierro MTG, Santamaria G (1991) Cromatografi*la y Te*lcnicas Afines 12(2):62

    Google Scholar 

  39. Gangoli N, Thodos G (1977) Ind. Eng. Chem. Prod. Res. Dev. 16:208

    Article  CAS  Google Scholar 

  40. Hawthorne SB (1990) Anal. Chem. 62:633A

    Article  CAS  Google Scholar 

  41. Sin CH, Linford MR, Goates SR (1992) Anal. Chem. 64:233

    Article  CAS  Google Scholar 

  42. Bysouth SR, Tyson JF (1992) Anal. Chim. Acta. 258:55

    Article  CAS  Google Scholar 

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© 1994 Springer-Verlag Berlin Heidelberg

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de Castro, M.D.L., Valcárcel, M., Tena, M.T. (1994). Physico — Chemical Properties of Supercritical Fluids. In: Analytical Supercritical Fluid Extraction. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78673-0_2

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  • DOI: https://doi.org/10.1007/978-3-642-78673-0_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78675-4

  • Online ISBN: 978-3-642-78673-0

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