Abstract
A supercritical fluid (SF) is a state where matter is compressible and behaves as a gas (i.e. it fills and takes the shape of its container), which is not the case when it is in a liquid state (an incompressible fluid that occupies the bottom of its container). However, a supercritical fluid has the typical density of a liquid (between 0.1 and l.0g/ml) and hence its characteristic dissolving power. Finally, an SF can also be defined as a heavy gas with a controllable dissolving power or as a form of matter in which the liquid and gaseous state are indistinguishable.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Berry RS, Rice SA, Ross J (1980) Phase equilibria in one-component systems. In: Physical chemistry. John Wiley
Shaw RW, Brill TB, Clifford AA, Eckert CA, Franck EU (1991) Supercritical water. A medium for chemistry. C&EN Special Report, pp. 23–26
Engelhardt H, Gross A (1991) Trends Anal. Chem. 10:64
McHugh M, Krukonis V (1986) Supercritical fluid extraction. Principles and practice. Butterworth, Stoneham, MA
Smith RD, Frye SL, Yonker CR, Gale RW (1987) J. Phys. Chem. 91:3059
Pitzer KS (1955) J. Am. Chem. Soc. 77:3427
Pitzer KS, Lippman DZ, Curl RF, Huggins CM Jr, Petersen DE (1955) J. Am. Chem. Soc. 77:3433
Langenfeld JJ, Hawthorne SB, Miller DJ, Tehrani J (1992) Anal. Chem. 64:2263
Supercritical fluid extraction and chromatography. Techniques and applications, Charpentier BA, Sevenants MR (eds). ACS Symposium Series 366, p. 130
Schneider GM, Stahl E, Wilke G (eds) Extraction with supercritical gases. Verlag Chemie, Weinheim, p. 73
Bruno TJ, Ely JF (1991) Supercritical fluid technology. Reviews in modern theory and applications. CRC Press
van Konynenburg PH, Scott RL (1980) Critical lines and phase equilibria in binary van der waals mixtures. Philos. Trans. Royal Soc. London 298:495
Schneider GM (1978) High-pressure phase diagrams and critical properties of fluid mixtures. In: Chemical thermodynamics, Vol. 2, Specialist periodical reports. The Chemical Society, London, 105
McHugh MA, Seckner AJ, Yogan TJ (1984) Ind. Eng. Chem. Fundam. 23:493
Rowlinson JS, Richardson MJ (1959) Adv. Chem. Phys. 2:85
Tehrani J, Myer L (1992) Supercritical fluid extraction method optimization using novel computer software. Pittcon’92, New Orleans
Reid RC, Prausnitz JM, Poling BE (1987) The properties of gases and liquids, 4th ed. McGraw-Hill Book Co. New York
Kamlet MJ, Abboud JL, Taft RW (1977) J. Am. Chem. Soc. 99:6027
Kamlet MJ, Abboud JL, Abraham MH, Taft RW (1983) J. Org. Chem. 48:2877
Sadek PC, Carr PW, Doherty RM, Kamlet MJ, Taft RW, Abraham MH (1985) Anal. Chem. 57:2971
Kim S, Johnston KP (1986) Effects of supercritical solvents on the rates of homogeneous chemical reactions. ACS Symp. Ser. 329:42
Smith RD, Wright BW, Yonker CR (1988) Anal. Chem. 60:1323A
Langenfeld JJ, Hawthorne SB, Miller DJ, Paschke T (1992) Comparison of fluids in supercritical fluid extraction (SFE). Pittcon’92, New Orleans
Ashraf-Khorassani M, Taylor LT, Zimmermann P (1990) Anal. Chem. 62:1177
Li SFY, Ong CP, Lee ML, Lee HK (1990) J. Chromatogr. 515:515
Huppert GL, Wu BC, Townsend SH, Klein MT, Paspek SC (1988) Hydrolysis in supercritical water identification and implications of a polar transition state. Ing. Eng. Chem. Res. 27:143
Larson KA, King ML (1986) Biotechnol. Prog. 2:73
Houser TJ, Tiffany DM, Li Z, McCarville ME, Houghton ME (1986) Fuel 65:827
Butler LG (1979) Enzyme Microb. Technol. 1:253
Zaks A, Klibanov AM (1984) Science 224:1249
Taniguchi M, Kamihira M, Kobayashi T (1987) Agric. Biol. Chem. 51:593
Randolph TW, Blanch HW, Prausnitz JM, Wilke CR (1985) Biotechnol. Lett. 7:325
Hammond DA, Karel M, Klibanov AM, Krukonis VJ (1985) Appl. Biochem. Biotechnol. 11:393
Scholsky KM (1987) Chemtech, 750
Capriel P, Haisch A, Khan SU (1986) J. Agric. Food Chem. 34:70
Hoyer GG (1985) Chemtech, 440
Hutchinson KW, Roebers JR, Thies MC (1991) Carbon 29:215
Hierro MTG, Santamaria G (1991) Cromatografi*la y Te*lcnicas Afines 12(2):62
Gangoli N, Thodos G (1977) Ind. Eng. Chem. Prod. Res. Dev. 16:208
Hawthorne SB (1990) Anal. Chem. 62:633A
Sin CH, Linford MR, Goates SR (1992) Anal. Chem. 64:233
Bysouth SR, Tyson JF (1992) Anal. Chim. Acta. 258:55
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1994 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
de Castro, M.D.L., Valcárcel, M., Tena, M.T. (1994). Physico — Chemical Properties of Supercritical Fluids. In: Analytical Supercritical Fluid Extraction. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78673-0_2
Download citation
DOI: https://doi.org/10.1007/978-3-642-78673-0_2
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-78675-4
Online ISBN: 978-3-642-78673-0
eBook Packages: Springer Book Archive