Abstract
We report adsorption studies on clean and modified surfaces of NiO, Cr2O3 and Al2O3. Small molecules such as NO, CO and H2O are adsorbed. The oxides are studied as bulk single crystals as well as as single crystal films. We are able to discriminate between adsorption on ideal terrace sites and defect sites by using EEL-spectra of surface states.
Employing various methods, e.g. ARUPS, HREELS and NEXAFS, we characterize the bonding between molecules and oxide substrates and show that concepts known from molecule metal interactions cannot directly be transferred to oxide surfaces.
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References
N.F. Mott, H. Jones: The Theory of the Properties of Metals and Alloys, Dover Publications, New York
S. Hüfher, J. Osterwalder, T. Riesterer, P. Hullinger: Solid State Commun. 52, 793 (1984)
S. Hüfher, P. Steiner, I. Sander, M. Neumann, S. Witzel: Z. Phys. B 83, 185 (1991)
H. Kuhlenbeck, H.-J. Freund in Metal-Ligand-Interactions: from atoms to clusters to surfaces, (Eds. D.R. Salahub, N. Russo), Nato advanced study institute, Series Vol. 378, p. 37 (1992), Kluwer Acad. Publishers
H. Kuhlenbeck, H.-J. Freund: Adsorption and reaction of small molecules on oxide surfaces, Springer Proceedings in Physics, in press
H.-J. Freund, Th. Mull, M. Menges, B. Baumeister, B. Adam, K. Al-Shamery, D. Weide, C. Fischer, P. Andresen: Low energy excitations and desoiption ynamics from oxide surfaces, in: Desorption induced by electronic transitions (DIET V), Springer Series in Surface Science, in press
H.-J. Freund, B. Dillmann, D. Ehrlich, M. Haßel, R.M. Jaeger, H. Kuhlenbeck, C.A. Ventrice Jr., F. Winkelmann, S. Wohlrab, C. Xu, Th. Bertram, A. Brodde, H. Neddermeyer: J. Mol. Catal., in press
H. Kuhlenbeck, G. Odörfer, R.M. Jaeger, G. Illing, M. Menges, Th. Mull, H.-J. Freund, M. Pöhlchen, V. Staemmler, S. Witzel, C. Scharfschwerdt, K. Wennemann, T. Liedtke, M. Neumann: Phys. Rev. B43, 1969 (1991)
St. Uhlenbrock, Chr. Scharfschwerdt, M. Neumann, G. Illing, H.-J. Freund: J. Phys. C 4, 7973 (1992)
M. Bäumer, D. Cappus, H. Kuhlenbeck, H.-J. Freund, G. Wilhelmi, A. Brodde, H. Neddermeyer: Surf. Sci. 253, 116 (1991)
M. Bäumer, D. Cappus, G. Illing, H. Kuhlenbeck, H.-J. Freund: J. Vac. Sci. Technol. A 10, 2407 (1992)
A. Freitag, V. Staemmler, D. Cappus, C.A. Ventrice Jr., K. Al-Shamery, H. Kuhlenbeck, H.-J. Freund: Chem. Phys. Lett., accepted
U.J. Katter, H. Schlienz, M. Beckendorf, H.-J. Freund: Ber. Bunsenges. Phys. Chem. 97, 340 (1993)
Th. Mull, B. Baumeister, M. Menges, H.-J. Freund, D, Weide, C. Fischer, P. Andresen: J. Chem. Phys. 96, 7108 (1992)
D. Cappus, C.A. Ventrice Jr., K. Al-Shamery, C. Xu, D. Ehrlich, H. Kuhlenbeck, H.-J. Freund: Chem. Phys., submitted
D. Cappus: Ph.D. thesis, Ruhr-Universität Bochum 1994
M. Menges: Ph.D. thesis, Ruhr-Universität Bochum 1993
C. Xu, B. Dillmann, H. Kuhlenbeck, H.-J. Freund: Phys. Rev. Lett. 67, 3551 (1991)
C. Xu, M. Haßel, H. Kuhlenbeck, H.-J. Freund: Surf. Sci. 258, 23 (1991)
H. Kuhlenbeck, B. Dillmann, M. Haßel, B. Adam, D. Ehrlich, S. Wohlrab, C. Xu, H.-J. Freund, U.A. Ditzinger, H. Neddermeyer, M. Neuber, M. Neumann: Ber. Bunsenges. Phys. Chem. 96, 15 (1992)
C.A. Ventrice Jr., D. Ehrlich, B. Dillmann, E.L. Garfunkel, H.-J. Freund: Phys. Rev. B46 12892 (1992)
D. Ehrlich, Ph.D. thesis, Ruhr-Universität Bochum 1994
M. Haßel, Ph.D. thesis, Ruhr-Universität Bochum 1994
R.M. Jaeger, H. Kuhlenbeck, H.-J. Freund, M. Wuttig, W. Hoffmann, R. Franchy, H. Ibach: Surf. Sci. 259, 235 (1991)
R.M. Jaeger, H. Kuhlenbeck, H.-J. Freund: Chem. Phys. Lett. 203, 41 (1993)
S. Wohlrab: Ph. D. thesis, Ruhr-Universität Bochum 1993
F. Winkelmann: Ph. D. thesis, Ruhr-Universität Bochum 1994
C.G. Kinniburgh, J.A. Walker: Surf. Sci. 63, 274 (1977)
St. Uhlenbrock, M. Neumann, D. Cappus, B. Dillmann, H.-J. Freund: unpublished results
M. Pöhlchen, V. Staemmler, J. Wasilewski: Surf. Sci., in press
L.G.M. Pettersson: to be published
V. Staemmler: this volume
C. Lin, T. Ito, J. Wang, J.H. Lunsford: J. Am. Chem. Soc. 109, 4808 (1987)
X. Zhang, R.K. Ungar, R.M. Lambert: J. Chem. Soc. Chem. Commun. 8, 473 (1989)
J. Libuda, S. Wohlrab, F. Winkelmann, M. Bäumer, H.-J. Freund: to be published
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Freund, HJ., Kuhlenbeck, H., Neumann, M. (1993). Molecular Adsorption on Thin Ordered Oxide Films and Single Crystal Oxide Surfaces. In: Freund, HJ., Umbach, E. (eds) Adsorption on Ordered Surfaces of Ionic Solids and Thin Films. Springer Series in Surface Sciences , vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78632-7_13
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DOI: https://doi.org/10.1007/978-3-642-78632-7_13
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