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Ionomer Solutions = Polyelectrolyte or Ionomer Behavior?

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Macromolecular Complexes in Chemistry and Biology

Abstract

For almost ten years the properties of ionomer solutions have been studied and lightly sulfonated polystyrene (S-PS) was chosen as the model compound. The properties of S-PS ionomer solutions in polar and nonpolar solvents, which are briefly reviewed, were associated with polyelectrolyte and ionomer behavior respectively. In both cases, structural models have been proposed to explain the rheological and scattering data. A similar study on perfluorinated ionomer solutions is then presented and compared in order to define some general ionomer behavior.

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References

  1. Hollyday L (1975) Ionic Polymers. Applied Science, London

    Google Scholar 

  2. Wilson AD, Professor HJ (eds) (1986) Developments in ionic polymers-2. Applied Science, London

    Google Scholar 

  3. Wilson AD, Prosser HJ (eds) (1983) Developments in ionic polymers-1. Applied Science, London

    Google Scholar 

  4. Eisenberg A, King M (1977) Ion-containing polymers. Academic, London

    Google Scholar 

  5. Rice SA, Nagasawa M (1961) Polyelectrolyte solutions. Academic, New York

    Google Scholar 

  6. Oosawa F (1971) Polyelectrolytes. Marcel Dekker, New York

    Google Scholar 

  7. Katchalsky A (1971) Pure and Applied Chem 26:327

    Article  CAS  Google Scholar 

  8. Selegny E, Mandel M, Strauss UP (eds) (1974) Charged and reactive polymers, vol I..D. Reidel, Dordrecht

    Google Scholar 

  9. Overbeek JThG (1976) Pure Appl Chem 46:91

    Article  CAS  Google Scholar 

  10. Manning GS (1969) J Chem Phys 51:924

    Article  CAS  Google Scholar 

  11. Eisenberg A (1970) Macromolecules 3:147

    Article  CAS  Google Scholar 

  12. Pineri M, Eisenberg A (eds) (1986) Structure an properties of ionomers. D. Reidel, Dordrecht

    Google Scholar 

  13. Lunderg RD (1987) Encyclopedia of Polymer Science, 2nd Ed 8:393

    Google Scholar 

  14. Coulter MO (ed) (1980) Modern chlor-alkali technology. Ellis Horwood, Chichester, England

    Google Scholar 

  15. Yeo SC, Eisenberg A (1977) J Appl Polym Sci 21:875

    Article  CAS  Google Scholar 

  16. Joanny JF (1988) Polymer 21:71

    Article  Google Scholar 

  17. Witten TA (1988) J Phys France 49:1055

    Article  CAS  Google Scholar 

  18. Broze G, Jerome R, Teyssie Ph, Marco C (1983) Macromolecules 16:996

    Article  CAS  Google Scholar 

  19. Broze G, Jerome R, Teyssie Ph (1982) Macromolecules 15:920

    Article  CAS  Google Scholar 

  20. Broze G, Jerome R, Teyssie Ph (1982) Macromolecules 15:1300

    Article  CAS  Google Scholar 

  21. Lundberg RD (1982) J Appl Polym Sci 27:4623

    Article  CAS  Google Scholar 

  22. Agarwal PK, Makowski, HS, Lundberg RD (1984) Macromolecules 17:1918

    Article  CAS  Google Scholar 

  23. Agarwal PK, Makowski HS, Lundberg RD (1984) Macromolecules 17:1929

    Google Scholar 

  24. Lundberg RD (1986) J Appl Polym Sci 31:1843

    Article  CAS  Google Scholar 

  25. Peiffer DG, Kim MW, Schulz DN (1987) J Polym Sci: Polym Phys Ed 25:1615

    Article  CAS  Google Scholar 

  26. Lundberg RD, Makowski HS (1980) J Polym Sci: Polym Phys Ed 18:1821

    Article  CAS  Google Scholar 

  27. Lundberg RD, Phillips RR (1982) J Polym Sci: Polym Phys Ed 20:1143

    Article  CAS  Google Scholar 

  28. Lundberg RD, Phillips RR (1984) Polymer Preprints 25(n°2):303

    CAS  Google Scholar 

  29. Kim MW, Peiffer DG (1985) J Chem Phys 83:4159

    Article  CAS  Google Scholar 

  30. Hara M, Wu JL, Lee AH (1988) Macromolecules 21:2214

    Article  CAS  Google Scholar 

  31. Agarwal PK, Garner RT, Graessley WW (1987) J Polym Sci: Polym Phys Ed 25:2095

    Article  CAS  Google Scholar 

  32. Hara M, Lee AH, Wu JL (1987) J Polym Sci: Polym Phys Ed 25:1407

    Article  CAS  Google Scholar 

  33. Hara M, Wu JL, Lee AH (1989) Macromolecules 22:754

    Article  CAS  Google Scholar 

  34. Rochas C, Domard A, Rinaudo M (1979) Polymer 20:76

    Article  CAS  Google Scholar 

  35. Peiffer DG, Lundberg RD (1984) J Polym Sci: Polym Phys Ed 22:1757

    Article  Google Scholar 

  36. Niezette J, Vanderschueren J, Aras L (1984) J Polym Sci: Polym Phys Ed 22:1757

    Article  Google Scholar 

  37. Peiffer DG, Kim MW, Kaladas J (1988) Polymer 29:716

    Article  CAS  Google Scholar 

  38. Eisenberg A, Rinaudo M (1990) Polym Bull 24:671

    Article  CAS  Google Scholar 

  39. Martenot JP, Galin JC, Picot C, Weill G (1989) J Phys France 50:493

    Article  CAS  Google Scholar 

  40. Joanny JF, Leibler L (1990) J Phys France 51:545

    Article  CAS  Google Scholar 

  41. Makowski HS, Lundberg RD, Shinghal G (1975) US Patent 3,870,841

    Google Scholar 

  42. Pedley AM, Higgins JS, Peiffer DG, Rennie AR, Staples E (1989) Polym Commun 30:162

    CAS  Google Scholar 

  43. Lantman CW, MacKnight WJ, Peiffer DG, Sinha SK, Lundberg RD (1987) Macromolecules 20:1096

    Article  CAS  Google Scholar 

  44. Pedley AM, Higgins JS, Peiffer DG, Burchard W (1990) Macromolecules 23:1434

    Article  CAS  Google Scholar 

  45. Hara M, Wu JL (1986) Macromolecules 19:2887

    Article  CAS  Google Scholar 

  46. Hara M, Wu JL (1988) Macromolecules 21:402

    Article  CAS  Google Scholar 

  47. Lantman CW, MacKnight WJ, Higgins JS, Peiffer DG, Sinha SK, Lundberg RD (1988) Macromolecules 21:1339

    Article  CAS  Google Scholar 

  48. Pedley AM, Higgins JS, Peiffer DG, Rennie AR (1990) Macromolecules 23:2494

    Article  CAS  Google Scholar 

  49. Dowling KC, Thomas JK (1991) Macromolecules 24:4123

    Article  CAS  Google Scholar 

  50. Fitzgerald JJ, Kim D, Weiss RA (1986) J Polym Sci: Polym Letters 24:263

    Article  CAS  Google Scholar 

  51. Ise N, Okubo T, Yamamoto K, Kawai H, Haschimoto T, Fujimura M, Hiragi Y (1980) J Am Chem Soc 102:7901

    Article  CAS  Google Scholar 

  52. Lipatov YS, Tsukruk VV, Dmitruk NV, Polyatskova NV, Shilov VV, Shevchenko VV (1983) Polymer Comm. 24:197

    CAS  Google Scholar 

  53. Lantman CW, MacKnight WJ, Higgins JS, Peiffer DG, Sinha SK, Lundberg RD (1988) Macromolecules 21:1344

    Article  CAS  Google Scholar 

  54. Wang J, Wang Z, Peiffer DG, Shuely WJ, Chu B (1991) Macromolecules 24:790

    Article  CAS  Google Scholar 

  55. Aldebert P, Novel-Cattin F, Pineri M, Millet P, Doumain C, Durand R (1989) Solid State Ionics 35:3

    Article  Google Scholar 

  56. Eisenberg A, Yeager HL (eds) (1982) Perfluorinated ionomer membranes. ACS Symp Ser 180, American Chemical Society, Washington

    Google Scholar 

  57. Grot WG, Chadds C (1982) European Patent 0 066 379

    Google Scholar 

  58. Gebel G, Aldebert P, Pineri M (1987) 20:1425

    Google Scholar 

  59. Moore RB, Martin CR (1988) Macromolecules 21:1334

    Article  CAS  Google Scholar 

  60. Gebel G (1989) Thèse Grenoble

    Google Scholar 

  61. Martin CR, Rubinstein J, Bard AJ (1982) J Am Chem Soc 104:4817

    Article  CAS  Google Scholar 

  62. Guglielmi M, Aldebert P, Pineri M (1989) J Appl Electrochem 19:167

    Article  CAS  Google Scholar 

  63. Aldebert P, Guglielmi M, Pineri M (1991) Polymer Journal 23:399

    Article  CAS  Google Scholar 

  64. Aldebert P, Pineri M (1986) French Patent 8 605 792

    Google Scholar 

  65. Aldebert P, Dreyfus B, Pineri M (1986) Macromolecules 19:2651

    Article  CAS  Google Scholar 

  66. de Gennes PG, Pincus P, Velasco R, Brochard F (1976) J Phys France 37:1461

    Article  Google Scholar 

  67. Aldebert P, Dreyfus B, Gebel G, Nakamura N, Pineri M, Volino F (1986) J Phys France 49:2101

    Article  Google Scholar 

  68. Loppinet B, Gebel G, Aldebert P, Pineri M, Williams CE, to be published

    Google Scholar 

  69. Gebel G, Loppinet B, Aldebert P, Pineri M (1991) Polymer Preprints 32(1):612

    CAS  Google Scholar 

  70. Aldebert P, Gebel G, Loppinet B, to be published

    Google Scholar 

  71. Schlick S, Gebel G, Pineri M, Volino F (1991) Macromolecules 24:3517

    Article  CAS  Google Scholar 

Download references

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© 1994 Springer-Verlag Berlin Heidelberg

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Gebel, G. (1994). Ionomer Solutions = Polyelectrolyte or Ionomer Behavior?. In: Dubin, P., Bock, J., Davis, R., Schulz, D.N., Thies, C. (eds) Macromolecular Complexes in Chemistry and Biology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78469-9_19

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  • DOI: https://doi.org/10.1007/978-3-642-78469-9_19

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78471-2

  • Online ISBN: 978-3-642-78469-9

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