Multistability in Molecules and Reactions

  • P. J. Plath
  • C. Stadler
Conference paper
Part of the Springer Series in Synergetics book series (SSSYN, volume 64)

Abstract

Regarding multistability in chemical systems, the level of individual molecules and the level of the kinetic/thermodynamic description have to be distinguished. The difference in the order of magnitude of these two chemical descriptions is about the Loschmidt number. Therefore multistability in the molecular system has to be discussed in terms of algebraic quantum mechanics, whereas multistability on the kinetic/thermodynamic level is fully described in terms of classical non-linear dynamic systems. Taking two well-known chemical examples — the mesomery of benzene and the catalytic oxidation of alcohols — we discuss multistability with respect to both of the descriptions.

Keywords

Combustion Entropy Enthalpy Benzene Haas 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1995

Authors and Affiliations

  • P. J. Plath
    • 1
  • C. Stadler
    • 2
  1. 1.Institute of Applied and Physical ChemistryUniversity of BremenGermany
  2. 2.Institute of Organic ChemistryUniversity of BremenGermany

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