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High-Temperature Superconductivity pp 84–144Cite as

Electronic Properties of High-Tc Superconductors

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Abstract

The superconducting properties of metals are essentially defined by their electronic properties in the normal state. Therefore studies of the latter are important in clarifying the mechanism of superconductivity in the new oxide superconductors. With respect to their electronic structure, these compounds may be related to the class of ionic semiconductors, in which the metallic conductivity appears upon the changes of stoichiometry. Their electronic structure is defined by a rather complicated interaction of localized and band electronic states, which is sensitive to short-range order in atomic positions. In this context, we will first discuss some crystallochemical aspects of electronic structure of oxide superconductors which are due to the individual properties of the constituent ions, and we will also con-sider the effect of impurity substitution on the electronic properties. The electronic structure is then discussed in greater detail on the basis of “first principles” and cluster-model electronic band calculations.

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Plakida, N.M. (1995). Electronic Properties of High-Tc Superconductors. In: High-Temperature Superconductivity. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78406-4_5

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