Skip to main content

A Record of Atmospheric Oxidant from Polar Ice Cores over the Past 100,000 Years: Dream or Real Possibility?

  • Conference paper
The Tropospheric Chemistry of Ozone in the Polar Regions

Part of the book series: NATO ASI Series ((ASII,volume 7))

Abstract

The principal oxidants of the earth’s atmosphere are O3, OH radical and H2O2. The total atmospheric burden of these three species determines the oxidation capacity of the atmosphere [Thompson, 1992]. Each of these species reacts with different atmospheric trace constituents, and determines their atmospheric lifetimes. In particular, the OH radical reacts very fast with almost all naturally and anthropogenically emitted species; therefore, this radical has the nickname “tropospheric vacuum cleaner” [Graedel, 1978].

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Bales, R. C., J. Dibb and A. Neftel, EOS Article, 1992.

    Google Scholar 

  • Chappellaz, J., J.M. Barnola, D. Raynaud, Y.S. Korotkevich and C. Lorius, Ice-core record of atmospheric methane over the past 160,000 years, Nature, 345, 127–131, 1990.

    Article  CAS  Google Scholar 

  • Conklin, M.H., A. Sigg, A. Neftel and R.C. Bales Atmosphere-Snow transfer function for H2O2: microphysical considerations, (submitted to JGR, August 1992 ).

    Google Scholar 

  • Dansgaard, W., S.J. Johnsen, H.B. Clausen, D. Dahl-Jensen, N. Gunderstrup, C. Hammer and H. Oeschger, North Atlantic climatic oscillations revealed by deep Greenland ice cores. In Climate Processes and Climate Sensitivity Geophysical Monograph 29 288–298, AGU, Washington DC, 1984.

    Chapter  Google Scholar 

  • Etheridge, D.M., G.I. Pearman, and F. de Silva, Atmospheric trace gas variations as revealed by air trapped in an ice core from Law Dome, Antarctica, Annuals of Glaciology, 10, 28–33, 1988.

    CAS  Google Scholar 

  • Fuhrer, K., A. Neftel, M. Anklin, M. Möll and V. Maggi, Continuous in situ measurements of chemical species along the new GRIP ice core from Summit, Central Greenland, (submitted).

    Google Scholar 

  • Graedel, T.E., Chemical compounds in the Atmosphere Academic Press, New York, 1978. Intergovernmental Panel in Climate Change ICPP, Climate Change - The IPCC Scientific Assessment, Press syndicate University of Cambridge, 1990.

    Google Scholar 

  • Johnsen, S.J., Stable Isotope Homogenization of Polar Firn and Ice, International Association of Hydrological Sciences Publication 118, Isotopes and Impurities in Snow and Ice, Grenoble, 210, 1977.

    Google Scholar 

  • Logan, J.A., Tropospheric Ozone: Seasonal behaviour, trends and anthropogenic influence, J. Geophys. Res., 90, 10463–10482, 1985.

    Article  Google Scholar 

  • Neftel, A.; P. Jacob and D. Klockow, Measurements of hydrogen peroxide in polar ice samples, Nature, 311, 43–45, 1984.

    Article  CAS  Google Scholar 

  • Neftel, A.; P. Jacob and D. Klockow, Long-term trend of Hydrogen Peroxide in polar ice cores, Tellus, 38B, 262–270, 1986.

    Article  CAS  Google Scholar 

  • Neftel, A., and A. Sigg, Hydrogen Peroxide in solid precipitation, Fourth European symposium on physico-chemical behaviour of atmospheric pollutants, D. Reidel Publ. Comp. 500–510, 1987.

    Google Scholar 

  • Neftel, A., Use of snow and firn analysis to reconstruct past atmospheric composition in: Seasonal Snowpacks - Processes of compositional changes. Eds., T.D. Davies, M. Tranter and H.G. Jones. Springer Verlag Series G: Ecological Sciences Vol. 8 385–416, 1990.

    Google Scholar 

  • Oeschger, H. and C.C. Langway Jr., The Environmental Record in Glaciers and Ice Sheets. Physical, Chemical and Earth Science Research Report 8, John Wiley & Son., 1989.

    Google Scholar 

  • Schwander, J. and B. Stauffer, Age difference between polar ice and the air trapped in its bubbles, Nature, 311, 45–47, 1984.

    Article  CAS  Google Scholar 

  • Sigg, A. and A. Neftel, Seasonal variations of hydrogen peroxide in polar ice cores. Annual Glaciol., 10, 157–162, 1988.

    CAS  Google Scholar 

  • Sigg, A., T. Staffelbach, and A. Neftel, Gas phase measurements of hydrogen peroxide in Greenland and their meaning for the interpretation of H2O2 records in ice cores, J. of Atmos. Chem., 14: 223–232, 1992.

    Article  CAS  Google Scholar 

  • Stauffer, B., G. Fischer, A. Neftel and H. Oeschger, Increase of atmospheric methane recorded in Antarctic ice core, Science, 229, 1386–1388, 1985.

    Article  CAS  Google Scholar 

  • Stauffer, B., E. Lochbrunner, H. Oeschger and J. Schwander, Methane concentration in the glacial atmosphere was only half that of the preindustrial Holocene, Nature, 332, 812–814, 1988.

    Article  CAS  Google Scholar 

  • Stauffer, B. and A. Neftel, What have we learned from the ice cores about atmospheric changes in the concentrations of nitrous oxide, hydrogen peroxide, and other trace species; The changing atmosphere, Eds. F. S. Rowland and I.S.A. Isaksen, John Wiley and Son 63–77 Dahlem Konferenzen, 1988.

    Google Scholar 

  • Staffelbach, T., A. Neftel, B. Stauffer and D. Jacob, Formaldehyde in polar ice cores; a possibility to characterize the atmospheric sink of methane in the past, Nature, 349, 603–605, 1991.

    Article  CAS  Google Scholar 

  • Thompson, A.M., The oxidizing capacity of the earth’s atmosphere: Probable past and future changes, Science, 256, 1157–1165, 1992.

    Article  CAS  Google Scholar 

  • Volz, A., and D. Kley, Ozone measurements made in the 19th century: An evaluation of the Montsouris series, Nature, 332, 240–242, 1988.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Neftel, A., Fuhrer, K. (1993). A Record of Atmospheric Oxidant from Polar Ice Cores over the Past 100,000 Years: Dream or Real Possibility?. In: Niki, H., Becker, K.H. (eds) The Tropospheric Chemistry of Ozone in the Polar Regions. NATO ASI Series, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78211-4_15

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-78211-4_15

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78213-8

  • Online ISBN: 978-3-642-78211-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics