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Quantum-Resolved Stimulated Surface Reactions

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Desorption Induced by Electronic Transitions DIET V

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 31))

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Abstract

Stimulated reactions of coadsorbates on Pt(111) surfaces have been probed using laser resonance-enhanced multiphoton ionization (REMPI) spectroscopy on the gas-phase neutral products. In particular, electron stimulated dissociation of N02(a) coadsorbed with up to 0.75 ML of atomic O on Pt(111) has been studied. Adding coadsorbed O to the surface enhances the specific dissociation yield, narrows the NO translational energy distribution, reduces the NO internal energy, and produces gas-phase O dissociation fragments. Reactive scattering between coadsorbates has also been studied. Specifically, NO2(d) production has been observed during electron-beam irradiation of NO coadsorbed with O2 on Pt(111). The NO2(d) was indirectly observed as NO(ν=5) and O(3Pj) gas-phase photodissociation fragments. We assign NO2 production to a collision between NO(a) and a hot O atom which was produced by electron-stimulated dissociation of adsorbed O2.

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References

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Authors and Affiliations

  1. Div. 1151, Sandia National Laboratories, Albuquerque, NM, 87185, USA

    T. M. Orlando, A. R. Burns, E. B. Stechel & D. R. Jennison

  2. Pacific Northwest Laboratory, Molecular Science Research Center K2-14, Richland, WA, 99352, USA

    T. M. Orlando

Authors
  1. T. M. Orlando
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  2. A. R. Burns
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  3. E. B. Stechel
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  4. D. R. Jennison
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Editor information

Editors and Affiliations

  1. Sandia National Laboratories, Albuquerque, P.O. Box 5800, Albuquerque, NM, 87185, USA

    Alan R. Burns , Ellen B. Stechel  & Dwight R. Jennison ,  & 

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© 1993 Springer-Verlag Berlin Heidelberg

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Orlando, T.M., Burns, A.R., Stechel, E.B., Jennison, D.R. (1993). Quantum-Resolved Stimulated Surface Reactions. In: Burns, A.R., Stechel, E.B., Jennison, D.R. (eds) Desorption Induced by Electronic Transitions DIET V. Springer Series in Surface Sciences, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78080-6_31

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  • DOI: https://doi.org/10.1007/978-3-642-78080-6_31

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78082-0

  • Online ISBN: 978-3-642-78080-6

  • eBook Packages: Springer Book Archive

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