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Intermolecular Interactions at Low Temperature. Matrix Isolation Spectroscopy Applied to Hydrogen-Bonded Complexes and Charge Transfer Complexes

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Intermolecular Forces

Abstract

Isolation of molecules, capable of undergoing specific intermolecular interactions with partner molecules, in inert solid matrices at extremely low temperature constitutes a unique experimental test for theoretical models or predictions which are usually based on the assumption of essentially “free” complexes. The technique offers many advantages compared to conventional spectroscopy, especially for H-bonded complexes. Detailed examples of matrix studies in this field are discussed. These include the vibrational correlation diagram for B…HCl complexes, the study of small aggregates of HCl, identification of the interaction site(s) in the polyfunctional bases methyl acetate and uracil, and the IR induced dissociation of the HI complex of dimethylacetamide.

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6 References

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Authors
  1. G. Maes
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Editors and Affiliations

  1. Department Scheikunde, Katholieke Universiteit Leuven, B-3030, Leuven (Haverlee), Belgium

    Pierre L. Huyskens  & Therese Zeegers-Huyskens  & 

  2. Physikalische Chemie und Zentrum für Materialwissenschaften, Philipps Universität, D-3550, Marburg, West-Germany

    Werner A. P. Luck

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© 1991 Springer-Verlag Berlin, Heidelberg

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Maes, G. (1991). Intermolecular Interactions at Low Temperature. Matrix Isolation Spectroscopy Applied to Hydrogen-Bonded Complexes and Charge Transfer Complexes. In: Huyskens, P.L., Luck, W.A.P., Zeegers-Huyskens, T. (eds) Intermolecular Forces. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76260-4_8

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  • DOI: https://doi.org/10.1007/978-3-642-76260-4_8

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-76262-8

  • Online ISBN: 978-3-642-76260-4

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