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The Influence of the Interionic Distance on the Cubic EPR Spectrum of Gd3+ Ion in RBCaF3 Single Crystals

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25th Congress Ampere on Magnetic Resonance and Related Phenomena

Abstract

The temperaature and hydrostatic dependences of the cubic EPR spectrum for Gd3+ in RbCaF3, has been investigated. It was found that the metal-ligand destance dependence of the b0 4 parameter can be described by the function type b0 4 ~ rR with k = -20. It was also found that vibronic effects contribute oominantly to the observed temperature dependence of b0 4.

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© 1990 Springer-Verlag Berlin Heidelberg

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Rewaj, T., Krupski, M., Buzaré, J.Y. (1990). The Influence of the Interionic Distance on the Cubic EPR Spectrum of Gd3+ Ion in RBCaF3 Single Crystals. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_19

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  • DOI: https://doi.org/10.1007/978-3-642-76072-3_19

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53136-4

  • Online ISBN: 978-3-642-76072-3

  • eBook Packages: Springer Book Archive

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