Abstract
It is demonstrated that the coupling between diffusion and macroscopic flow becomes important in various situations of polymer solutions. A phenomenological constitutive equation which describes this effect is proposed. As an application, two problems are discussed: (i) viscoelastic effect in the swelling process of polymer solutions, and (ii) concentration gradient in the rheometrical shear flow in parallel plate and cone-and-plate geometries.
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© 1990 Springer-Verlag Berlin Heidelberg
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Doi, M. (1990). Effects of Viscoelasticity on Polymer Diffusion. In: Onuki, A., Kawasaki, K. (eds) Dynamics and Patterns in Complex Fluids. Springer Proceedings in Physics, vol 52. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76008-2_18
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DOI: https://doi.org/10.1007/978-3-642-76008-2_18
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-76010-5
Online ISBN: 978-3-642-76008-2
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