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Solubility and Adsorption Effects in Polymer HPLC

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Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation

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Abstract

It has been stated “that normal chromatographic retention and precipitation/redissolution represent two processes, either of which can determine chromatographic retention in a given case” [1]. This chapter deals with the methods of finding out whether or not one of the mechanisms in question predominates. Information on the mechanismus of a given polymer separation can be derived (i) from the dependence of retention time on sample size, (ii) by comparison between solubility and elution characteristics, (iii) from a closer inspection of the chromatographic system that affects separation, and (iv) from the effect of temperature on retention.

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Authors and Affiliations

  1. Technische Universität Dresden, Mommsenstr. 13, O-8027, Dresden, Germany

    Professor Dr. Gottfried Glöckner

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  1. Professor Dr. Gottfried Glöckner
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© 1991 Springer-Verlag Berlin Heidelberg

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Glöckner, G. (1991). Solubility and Adsorption Effects in Polymer HPLC. In: Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75799-0_5

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  • DOI: https://doi.org/10.1007/978-3-642-75799-0_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-75801-0

  • Online ISBN: 978-3-642-75799-0

  • eBook Packages: Springer Book Archive

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