Abstract
On July 29, 1823, J.W. Doebereiner, professor of chemistry at the University of Jena, informed his minister, J.W. Goethe, about his observation that finely divided platinum causes hydrogen to react with oxygen “by mere contact”, whereby the platinum even starts to glow due to the heat evolved in this process [1.1]. This discovery was a sensation in the scientific world (perhaps comparable to the turmoil about recent reports about the so-called “cold fusion”, with the essential difference that Doebereiner’s effect was real!) and prompted many researchers to further investigations in this field, for which somewhat later Berzelius coined the term “catalysis” [1.2]. A tentative explanation was offered by Faraday [1.3] who speculated:
“dependent upon the natural conditions of gaseous elasticity combined with the exertion of that attractive force possessed by many bodies …; by which they are drawn into association more or less close, … and which occasionally leads to the combination of bodies simultaneously subjected to this attraction”.
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References
A Mittasch: Döbereiner, Goethe und die Katalyse, (Hippokrates, Stuttgart 1951)
J. Berzelius Jber. Chem. 15, 1936 (237)
H.S. Taylor: Trans. Faraday Soc. 28 (1932), 131
W. Ostwald: Physik. Z. 3 (1902), 313
I Langmuir: Laboratory Notebook February 2, 1915.
Quoted from G.L. Gaines, G. Wise: In Heterogeneous Catalysis-Selected American Histories, ed. by B.H. Davis, W.P. Hettinger, American Chem. Society (1983), p. 13
ibid., April 21, 1915
I. Langmuir: J. Am. Chem. Soc. 38 (1916), 2221
I. Langmuir: Trans. Faraday Soc. 17 (1922), 607
G. Ertl: Surface Sci. 6 (1967), 208
D. Coulman, J. Wintterlin, R.J. Behm, G. Ertl: Phys. Rev. Lett. 64 (1990), 1761 and in preparation
G.W. Simmons, D.F. Mitchell, K.R. Lawless: Surface Sci. 8 (1967), 130
R.P.N. Bronckers, A.GJ. de Wit: Surface Sci. 12 (1981), 133
J.A. Yarmoff, D.M. Cyr, J.H. Huang, R.S. Williams: Phys. Rev. B33 (1986), 3856
E. van de Riet, J.B J. Smeeb, J.M. Fluit, A. Niehaus: Surface Sci. 214 (1989), 111
R.N. Niehus, G. Comsa: Surface Sci. 140 (1984), 18
Spitzer, H. Liith: Surface Sci. 118 (1982), 121
I.E. Wachs, R.J. Madix: Appl. Surface Sci. 40 (1973), 545
F.H.P.M. Habraken, G.A. Bootsma: Surface Sci. 87 (1979), 333
F.H.P.M. Habraken, G.A. Bootsma, P. Hofmann, S. Hachicha: Surface Sci. 88 (1979), 285
J.F. Wendelken: Surface Sci. 108 (1981), 605
J. Lapujoulade, Y. Le Cruer, M. Lefort, Y. Lejay, E. Maurel: Surface Sci. 118 (1982), 103
A.G.J. de Wit, R.P.N. Bronckers, J.M. Fluit: Surface Sci. 82 (1979), 177; 90 (1979), 676; 104 (1981), 384
M. Bader, A. Puschmann, C. Ocal, J. Haase: Phys. Rev. Lett. 57 (1986), 3273
R.A. Di Dio, D.M. Zehner, E.W. Plummer: J. Vac. Sci. Technol. A2 (1984), 852
R. Courths, B. Cord, H. Wem, H. Saalfeld, S. Hüfher: Solid State Commun. 63 (1987), 619
A.W. Robinson, J.S. Somers, D.E. Ricken, A.M. Bradshaw, A.L.D. Kilcoyne, D.P. Woodruff: to be published
U. Döbler, K. Baberschke, J. Haase, A. Puschmann: Phys. Rev. Lett. 52 (1984), 1437
R. Feidenhans’l, I. Stensgard: Surface Sci. 133 (1983), 453
K.S. Liang, P.H. Fuoss, G.J. Hughes, P. Eisenberger: in The Structure of Surfaces, ed. by M.A. Van Hove, S.Y. Tong (Springer, Berlin, Heidelberg 1985) p.245
J.A. Stroscio, M. Persson, W. Ho: Phys. Rev. B33 (1986), 6758
Hillert, L. Becker, M. Pedio, J. Haase, to be published
F.M. Chua, Y. Kuk, PJ. Silvermann: Phys. Rev. Lett. 63 (1989), 386
G. Kleinle, J. Wintterlin, G. Erti, R.J. Behm, F. Jona, W. Moritz: Surface Sci. 225 (1990), 171
G. Kleinle, W. Moritz, D.L. Adams, G. Erti: Surface Sci. 219 (1989), L637
R.J. Behm, K. Christmann, G. Erti: Surface Sci. 99 (1980), 320;
K. Binder, D.P. Landau: Surface Sci. 108 (1981), 503
R. Imbihl, RJ. Behm, K. Christmann, G. Erti, T. Matsushima: Surface Sci. 117 (1982), 257;
W. Kinzel, W. Selke, K. Binder: Surface Sci. 121 (1982), 13;
W. Kinzel, W. Selke, K. Binder: Surface Sci. 125 (1983), 74;
W. Moritz, R. Imbihl, RJ. Behm, G. Erti, T. Matsushima: J. Chem. Phys. 83 (1985), 1959
R. J. Behm, P.A. Thiel, P.R. Norton, G. Erti: J. Chem. Phys. 78 (1983), 7438; 7448
P. Heilmann, K. Heinz, K. Müller: Surface Sci. 83 (1979), 487;
M.A. Van Hove, R.J. Koestner, P.C. Stair, J.P. Biberian, L.K. Kesmodel, I. Bartos, G.A. Somorjai: Surface Sci. 103 (1981), 189
K. Heinz, E. Lang, K. Strauss, K. Müller: Appi. Surface Sci. 11/12 (1982), 611;
P.R. Norton, J.A. Davies, D.K. Creber, C.W. Sitter, T.E. Jackman: Surface Sci. 108 (1981), 205
C.M. Comrie, R.M. Lambert: J. Chem. Soc. Farad. I72 (1986), 1659
T.E. Jackman, J.A. Davies, D.P. Jackson, W.N. Unertland, P.R. Norton: Surface Sci. 120 (1982), 389
H.P. Bonzel, S. Ferrer: Surface Sci. 118 (1982), L263
R. Imbihl, S. Ladas, G. Erti: Surface Sci. 206 (1988), L903
P. Hofmann, S.R. Bare, D.A. King, Surface Sci. 117 (1982) 245; 144 (1984), 347
B.E. Hayden, A.W. Robinson, P.M. Tucker: Surface Sci. 192 (1987), 163
P. Fenter, T. Gustaffson: Phys. Rev. B 38 (1988), 10197
N. Freyer, M. Kiskinova, G. Pirug, H.P. Bonzel: Appi. Phys. A 39 (1986), 209
T. Gritsch, D. Coulman, R.J. Behm, G. Erti: Phys. Rev. Lett. 63 (1989), 1086
M. Polanyi: Z. Elektrochem. 27 (1921), 142; 35 (1929), 561
H.S. Taylor: J. Am. Chem. Soc. 53 (1931), 578
G. Ehrlich: In Chemistry and Physics of Solid Surfaces VII, ed. by R. Vanselow, R.F. Howe (Springer, Berlin, Heidelberg 1988) p.l
J.E. Lennard-Jones: Trans. Faraday Soc. 28 (1932), 333
M. Polanyi, H. Eyring: Z. Phys. Chem. 12B (1931), 279
See e.g. G. Erti: Proc. Solvay Conf. on Surface Science, ed. by F.W. De Wette (Springer, Berlin, Heidelberg 1988), p. 322
Langmuir, Trans. Faraday Soc. 17 (1922), 621
M. Bodenstein, F. Ohlmer: Z. Phys. Chem. 53 (1905), 166
M. Bodenstein, C.G. Fink: Z. Phys. Chem. 60 (1907), 1
G. Erti, P. Rau: Surface Sci. 15 (1969), 443
T. Engel, G. Erti: Adv. Catalysis 28 (1979), 1
T. Engel, G. Erti: J. Chem. Phys. 69 (1978), 1267;
C.T. Campbell, G. Erti, H. Kuipers, J. Segner: J. Chem. Phys. 73 (1980), 5862
G. Erti: In Chemistry and Physics of Solid Surfaces III, ed. by R. Vanselow, W. England (CRC Press 1982), p.19
S.H. Oh, G.B. Fisher, J.E. Carpenter, D.W. Goodman: J. Catal. 100 (1986), 360;
A.G. Sault, D.W. Goodman: Adv. Chem. Phys. 76 (1989), 153
G. Erti: In Catalysis-Science and Technology, ed. by J.R. Anderson, M. Boudart, Vol.4 (Springer, Berlin, Heidelberg 1983), p.209
P. Stoltze, J.K. Nørskov: Phys. Rev. Lett. 55 (1985), 2502;
P. Stoltze, J.K. Nørskov: Surface Sci. 197 (1988), L230;
M. Bowker, I. Parker, K. Waugh: Surface Sci. 197 (1988), L223;
J.A. Dumesic, A.A. Trevino, to be published
M. Boudart, to be published
S. Ladas, R. Imbihl, G. Erti: Surface Sci. 197 (1988), 153
M. Flytzani-Stephanopoulos, L.D. Schmidt: Progr. Surf. Sci. 9 (1979), 83
R. Imbihl, A.E. Reynolds, D. Kaletta, to be published
G. Erti, Adv. Catalysis 37 (1990), in press
G. Nicolis, I. Prigogine: Self-Organisation in Nonequilibrium Systems (Wiley, New York 1977)
A.M. Turing: Phil. Trans. Roy. Soc. (London) B237 (1952), 37
M. Eiswirth, G. Erti: Surf. Sci. 177 (1986), 90
P. Hugo: Ber. Bunsenges. Phys. Chem. 74 (1970), 121;
H. Beusch, P. Fieguth, E. Wicke: Chem. Ing. Techn. 44 (1972), 445
For recent review see L.F. Razón, R.A. Schmitz: Catal. Rev. 28 (1986), 89;
L.F. Razón, R.A. Schmitz: Chem. Eng. Sci. 42 (1987), 1005
G. Erti, P.R. Norton, J. Rüstig: Phys. Rev. Lett. 49 (1982), 177
R. Imbihl, to be published (review)
O. Gurel, D. Gurel: Oscillations in Chemical Reactions Springer, Berlin, Heidelberg 1983
M.P. Cox, G. Erti, R. Imbihl, J. Rüstig: Surface Sci. 134 (1983), L517;
R. Imbihl, M. P. Cox, G. Erti: J. Chem. Phys. 84 (1986), 3519
M. Eiswirth, R. Schwankner, G. Erti: Z. Phys. Chem. N. F. 144 (1985), 59
M. Eiswirth, P. Möller, K. Wetzl, R. Imbihl, G. Erti: J. Chem. Phys. 90 (1989), 510
R. Imbihl, S. Ladas, G. Erti: Surface Sci. 219 (1989), 88
M. Ehsasi, C. Seidel, H. Ruppender, W. Drachsel, J.H. Block, K. Christmann: Surface Sci. 210 (1989), L198
N.A. Collins, S. Sundaresan, Y.J. Chabal: Surface Sci. 180 (1987), 136
R. Imbihl, M. P. Cox, G. Erti, H. Müller, W. Brenig: J. Chem. Phys. 83 (1985), 1578
K. Krischer: thesis, in preparation
M. Eiswirth, K. Krischer, G. Erti: Surface Sci. 202 (1988), 565
M. Eiswirth, G. Erti: Phys. Rev. Lett. 60 (1988), 1526;
M. Eiswirth, P. Möller, G. Erti: Surface Sci. 208 (1989), 13
S.B. Schwartz, L.D. Schmidt: Surface Sci. 183 (1987) L269; 206 (1988), 169;
M.R. Bassett, J.P. Dath, T. Fink, R. Imbihl, G. Erti: to be published
M. P. Cox, G. Erti, R. Imbihl: Phys. Rev. Lett. 54 (1985), 1725
H.H. Rotermund, G. Erti, W. Sesselmann: Surface Sci. 217 (1989), L383
H.H. Rotermund, S. Jakubith, A. von Oertzen, S. Kubala, G. Erti: J. Chem. Phys. 91 (1989), 4942
T. Fink, R. Imbihl, G. Erti: J. Chem. Phys. 91 (1989), 5002
R. Luther: Z. Elektrochem. 12 (1906), 596
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Ertl, G. (1990). Reactivity of Surfaces. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces VIII. Springer Series in Surface Sciences, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75762-4_1
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