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Hydrothermal Alteration

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Hydrothermal Mineral Deposits

Abstract

Hydrothermal alteration is a very complex process involving mineralogical, chemical and textural changes, resulting from the interaction of hot aqueous fluids with the rocks through which they pass, under evolving physico-chemical conditions. Alteration can take place under magmatic subsolidus conditions by the action and infiltration of supercritical fluids into a rock mass. At lower temperature and pressure, exsolution of gas and aqueous phases constitute hydrothermal solutions which act on the surrounding rocks, producing changes as the result of disequilibrium, largely due to H+ and OH- and other volatile constituents (e.g. B, CO2, F).

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References

  • Babcock R S (1973) Computational models of metasomatic processes. Lithos 6: 279–290

    Article  Google Scholar 

  • Batchelor R A, Bowden P (1985) Petrogenetic interpretation of granitoid rock series using multicationic parameters. Chem Geol 48: 43–55

    Article  Google Scholar 

  • Best, M G (1982) Igneous and metamorphic petrology. Freeman, San Francisco, New York, 630 pp

    Google Scholar 

  • Bonatti E (1978) The origin of metal deposits in the oceanic lithosphere. Sci Am 238: 54–61

    Article  Google Scholar 

  • Bowden P (1985) The geochemistry and mineralisation of alkaline ring complexes in Africa (a review). J Afr Earth Sci 3: 17–40

    Article  Google Scholar 

  • Bowden P, Kinnaird J A, Abaa S I, Ike E C, Turaki U M (1984) Geology and mineralisation of the Nigerian anorogenic ring complexes. Geol Yahrb 56: 1–68

    Google Scholar 

  • Brogger W C (1921) Die Eruptivgesteine des Kristianiagebiets IV. Das Fengebiet in Telemarken, Norwegen. Nors Vidensk Akad Oslo Skr Mat Nat 9: 408

    Google Scholar 

  • Burnham C W, Ohmoto H (1980) Late stage processes of felsic magmatism. In: Ishihara S, Takenouchi S (eds) Granitic magmatism and related mineralisation. Soc Min Geol Jpn 8: 1–11

    Google Scholar 

  • Burt D M (1981) Acidity-salinity diagrams - Application to greisen and porphyry deposits. Econ Geol 76: 832–843

    Article  Google Scholar 

  • Camus F (1975) Geology of the El Teniente orebody with emphasis on wall-rock alteration. Econ Geol 70: 1341–1372

    Article  Google Scholar 

  • Carmichael I S E, Turner F J, Verhoogen J (1974) Igneous petrology. McGraw-Hill, New York, 739 pp

    Google Scholar 

  • Criss R E, Taylor H P (1986) Meteoric-hydrothermal systems. In: Valley J W, Taylor H P, O’Neil J R (eds) Stable isotopes in high temperature geological processes. Reviews in mineralogy, vol 16. Min Soc Am, pp 373–424

    Google Scholar 

  • Crocker I T (1985) Volcanogenic fluorite-hematite deposits and associated pyroclastic rock suite at Vergenoeg, Bushveld Complex. Econ Geol 80: 1181–1200

    Article  Google Scholar 

  • Deer W A, Howie R A, Zussman J (1967) Rock forming minerals, vol 3. Longmans, London, 270 pp

    Google Scholar 

  • De la Roche.H, Leterrier J, Grand Claude P, Marchai M (1980) A classification of volcanic and plutonic rocks using R1–R2 diagrams and major element analyses - its relationship with current nomenclature. Chem Geol 29: 183–210

    Article  Google Scholar 

  • Dietrich R V (1985) The tourmaline group. Van Nostrand Reinhold, New York, 300 pp

    Google Scholar 

  • Economic Geology (ed) (1974) Stable isotopes as applied to problems of ore deposits. Econ Geol 69, 6

    Google Scholar 

  • Economic Geology (ed) (1983) An issue devoted to techniques and results of remote sensing. Econ Geol 78, 4

    Google Scholar 

  • Edmond J M, von Damm K (1983) Hot springs on the ocean floor. Sci Am 248: 70–85

    Article  Google Scholar 

  • Einaudi M T, Meinert L D, Newberry R J (1981) Skarn deposits. Econ Geol 75th Anniv Vol: 317–391

    Google Scholar 

  • Evans A M (1987) An introduction to ore geology, 2nd edn. Blackwell, Oxford, 358 pp

    Google Scholar 

  • Faure G (1986) Principles of isotope geology, 2nd edn. John Wiley & Sons, New York, 589 pp

    Google Scholar 

  • Felsche J, Herrmann, A G (1978) Yttrium and lanthanides. In: Wedepohl K H (ed) Handbook of Geochemistry, vol II/5. Springer, Berlin, Heidelberg, New York, pp 57–71-0

    Google Scholar 

  • Ferry J M (1983) Regional metamorphism of the Vassalboro Formation, south-central Maine, USA: a case study of the role of fluid in metamorphic petrogenesis. J Geol Soc London 140: 551–576

    Article  Google Scholar 

  • Ford J H (1978) A chemical study of alteration at the Panguna porphyry copper deposit, Bougainville, Papua New Guinea. Econ Geol 73: 703–720

    Article  Google Scholar 

  • Gladwell D R, Lett R E, Lawrence P (1983) Application of reflectance spectrometry to mineral exploration using portable radiometers. Econ Geol 78: 699–710

    Article  Google Scholar 

  • Goetz A F H, Rock B N, Rowan L C (1983) Remote sensing for exploration: An overview. Econ Geol 78: 573–590

    Google Scholar 

  • Grant J A (1986) The isocon diagram - A simple solution to Gresens equation for metasomatic alteration. Econ Geol 81: 1976–1982

    Article  Google Scholar 

  • Green G R, Ohmoto H, Date J, Takahashi T (1983) Whole-rock oxygen isotope distribution in the Fukazawa-Kosaka area, Hokoruku District, Japan, and its potential application to mineral exploration. Econ Geol Monogr 5: 395–411

    Google Scholar 

  • Gregory R T, Criss R E (1986) Isotopic exchange in open and closed systems. In: Valley J W, Taylor H P, O’Neil J R (eds) Stable isotopes in high temperature processes. Reviews in mineralogy, vol 16. Min Soc Am, pp 91–128

    Google Scholar 

  • Gresens R L (1967) Composition-volume relationships of metasomatism. Chem Geol 2: 47–65

    Article  Google Scholar 

  • Guilbert J M, Park C F (1986) The geology of ore deposits. Freeman, New York, San Francisco, 985 pp

    Google Scholar 

  • Hanson G N (1980) Rare earth elements in petrogenetic studies of igneous systems. Annu Rev Earth Planet Sci 8: 371–406

    Article  Google Scholar 

  • Hardie L A (1987) Dolomitisation: A critical view of some current views. J Sediment Petrol 57: 166–183

    Google Scholar 

  • Hemley J J, Jones W R (1964) Chemical aspects of hydrothermal alteration with emphasis on hydrogen metasomatism. Econ Geol 59: 538–569

    Article  Google Scholar 

  • Hemley J J, Hostetler P B, Gude A J, Mountjoy W T (1969) Some stability relations of alunite. Econ Geol 64: 599–612

    Article  Google Scholar 

  • Hemley J J, Montoya J W, Marinenko J W, Luce R W (1980) Equilibria in the system Al2O3-SiO2-H2O and some general implications for alteration/mineralisation processes. Econ Geol 75: 210–228

    Article  Google Scholar 

  • Henley R W, Ellis A J (1983) Geothermal systems ancient and modern: a geological review. Earth Sci Rev 19: 1–50

    Article  Google Scholar 

  • Hunt G R, Ashley R P (1979) Spectra of altered rocks in the visible and near infrared. Econ Geol 74: 1613–1629

    Article  Google Scholar 

  • Hunt G R, Salisbury J W (1970) Visible and near-infrared spectra of minerals and rocks: I. Silicate minerals. Modern Geol 1: 283–300

    Google Scholar 

  • Hunt G R, Salisbury J W (1971) Visible and near-infrared spectra of minerals and rocks: II Carbonates. Modern Geol 2: 23–30

    Google Scholar 

  • Hunt G R, Salisbury J W, Lenhoff C J (1971) Visible and near-infrared spectra of minerals and rocks: III. Oxides and hydroxides. Modern Geol 2: 195–205

    Google Scholar 

  • Keays R R, Nickel E H, Groves D I, McGoldrick P J (1982) Iridium and palladium as discriminants of volcanic-exhalative hydrothermal, and magmatic nickel sulfide mineralisation. Econ Geol 77: 1535–1547

    Article  Google Scholar 

  • Kinnaird J A (1985) Hydrothermal alteration and mineralisation of the alkaline anorogenic ring complexes of Nigeria. J Afr Earth Sci 3: 229–252

    Article  Google Scholar 

  • Kirwin D J (1985) Tourmaline breccia pipes. Msc Thesis, James Cook Univ, N Queensl, 139 pp

    Google Scholar 

  • Larson P B, Taylor H P (1986) 180/160 relationships in hydrothermally altered rocks from the Lake City caldera, San Juan Mountains, Colorado. J Volcanol Geothermal Res 30: 47–82

    Google Scholar 

  • Leblanc M, Lbouabi M (1988) Native silver mineralisation along a rodingite tectonic contact between serpentinite and quartz-diorite ( Bon Azzer, Morocco). Econ Geol 83: 1379–1391

    Google Scholar 

  • Lillesand T M, Kiefer R W (1987) Remote sensing and image interpretation, 2nd edn. John Wiley & Sons, New York, 612 pp

    Google Scholar 

  • Lottermoser B L (1990) Rare-earth element and heavy metal behaviour associated with the epithermal gold deposit on Lihir Island, Papua New Guinea. J Volcanol Geothermal Res 40: 269–289

    Article  Google Scholar 

  • Lovering T G, Heyl A (1974) Jasperoid as a guide to mineralization in the Taylor mining district and vicinity near Ely, Nevada. Econ Geol 69: 46–58

    Google Scholar 

  • Martini J E J (1988) As-Zn mineralisation associated with a Proterozoic geothermal system in the Rooiberg Group. S Afr J Geol 91: 337–345

    Google Scholar 

  • McGregor G J (1986) Geology of the Black Mountain orebody. In: Abstr Geocongress ’86, Johannesburg. Geol Soc S Afr, pp 1025–1028

    Google Scholar 

  • MacKenzie I F (1983) Geology and geochemistry of tungsten mineralisation at Doctor Hill and Falls creek, Central Westland, New Zealand. MsC thesis, Victoria Univ, Wellington, 160 pp

    Google Scholar 

  • McLeod R L, Stanton R L (1984) Phyllosilicate and associated minerals in some Paleozoic stratiform sulfide deposits of south-eastern Australia. Econ Geol 79: 1–22

    Article  Google Scholar 

  • Meyer C, Hemley J J (1967) Wall rock alteration. In: Barnes H L (ed) Geochemistry of hydrothermal ore deposits, 1st edn. Holt Rinehart & Winston, New York, pp 166–235

    Google Scholar 

  • Michard A (1989) Rare earth element systematics in hydrothermal fluids. Geochim Cosmochim Acta 53: 745–750

    Article  Google Scholar 

  • Minnitt RCA (1986) Porphyry copper-molybdenum mineralisation at Haib river, South West Africa/Namibia. In: Anhaeusser C R, Maske S (eds) Mineral deposits of southern Africa, vol 2. Geol Soc S Afr, pp 1567–1585

    Google Scholar 

  • Moore W J, Nash J T (1974) Alteration and fluid inclusion studies of the porphyry copper orebody at Bingham, Utah. Econ Geol 69: 631–645

    Google Scholar 

  • Morrow D W (1982a) Diagenesis 1. Dolomite — Part 1: The chemistry of dolomitisation and dolomite precipitation. Geosci Can 9: 5–13

    Google Scholar 

  • Morrow D W (1982b) Diagenesis 2. Dolomite-Part2: dolomitizing models and ancient dolostones. Geosci Can 9: 95–107

    Google Scholar 

  • Muecke G K, Moller P (1988) The not-so-rare earths. Sci Am 258: 62–67

    Article  Google Scholar 

  • Nash J T, Granger H C, Adams S S (1981) Geology and concepts of genesis of important types of uranium deposits. Econ Geol 75th Anniv Vol: 63–116

    Google Scholar 

  • Ohmoto H (1986) Stable isotope geochemistry of ore deposits. In: Valley J W, Taylor H P, O’Neil J R (eds) Stable isotopes in high temperature geological processes. Reviews in mineralogy, vol 16. Min Soc Am, pp 491–560

    Google Scholar 

  • Pearton T N, Viljoen M J (1986) Antimony mineralisation in the Murchison greenstone belt. In: Anhaeusser C R, Maske S (eds) Mineral deposits of Southern Africa, vol 1. Geol Soc S Afr pp 293–321

    Google Scholar 

  • Phillips G N (1986) Geology and alteration in the Golden Mile, Kalgoorlie, Econ Geol 81: 779–808

    Article  Google Scholar 

  • Phillips G N, Groves D I (1982) Fluid access and fluid-wallrock interaction in the genesis of the Archean gold-quartz vein deposit at Hunt Mine, Kambalda, Western Australia. In: Foster R P (ed) Proc Symp Gold ’82. Geol Soc Zimb Spec Publ 1, pp 389–416

    Google Scholar 

  • Pirajno F, Jacob R E (1987) Sn-W metallogeny in the Damara Orogen, South West Africa/Namibia. S Afr J Geol 90: 239–255

    Google Scholar 

  • Pirajno F, Jacob R E (1988) Gold mineralisation in the intracontinental branch of the Damara Orogen, Namibia. In: Bicentennial Gold ’88, Geol Soc Aust Abstr Ser 23: 168–171

    Google Scholar 

  • Pirajno F, Schlogl H U (1987) The alteration-mineralisation of the Krantzberg tungsten deposit, South West Africa/Namibia. S Afr J Geol 90: 499–508

    Google Scholar 

  • Pirajno F, Smithies R H (in press) The FeO/FeO + MgO ratio of tourmaline: a useful indicator of spatial variations in granite-related hydrothermal mineral deposits. J Geochem Expl

    Google Scholar 

  • Plimer I R (1987) The association of tourmalinite with stratiform scheelite deposits. Mineral Depos 22: 82–291

    Article  Google Scholar 

  • Plimer I R (1988) Reply to the discussion by R H Smithies and F Pirajno: The association of tourmalinite with stratiform scheelite deposits. Mineral Depos 23: 314–315

    Article  Google Scholar 

  • Plimer IR, Kleeman J D (1986) Major and minor element chemistry of biotites in Mole granite, New South Wales, Australia. Trans Inst Min Metall 95: B1–B5

    Google Scholar 

  • Prins P (1981) The geochemical evolution of the alkaline and carbonatite complexes of the Damaraland igneous province, South West Africa. Ann Univ Stellenbosch Ser Al Geol 3: 145–278

    Google Scholar 

  • Roberts D E, Hudson,G R T (1983) The Olympic Dam copper-uranium-gold deposit, Roxby Downs, South Australia. Econ Geol 78: 799–822

    Google Scholar 

  • Rose A W, Burt D M (1979) Hydrothermal alteration. In: Barnes H L (ed) Geochemistry of hydrothermal ore deposits. John Wiley & Sons, New York, pp 173–227

    Google Scholar 

  • Rozendaal A, Stumpfl E F (1984) Mineral chemistry and genesis of Gamsberg zinc deposit, South Africa. Trans Inst Min Metall 93: B161–B175

    Google Scholar 

  • Ryan P J, Lawrence A L, Lipson R D, Moore J M, Paterson A, Stedman DP, Van Zyl D (1986) The Aggeneys base metal sulphide deposit, Namaqualand district. In: Anhaeusser C R, Maske S (eds) Mineral deposits of Southern Africa, vol 2. Geol Soc S Afr, pp 1447–1473

    Google Scholar 

  • Sheppard S M F (1986) Characterization and isotopic variations in natural waters. Reviews in mineralogy, vol 16. Min Soc Am, pp 165–183

    Google Scholar 

  • Siems P (1984) Hydrothermal alteration for mineral exploration workshop. Lecture Manual, Dep Geol Univ Witwatersrand, Johannesburg, S Afr

    Google Scholar 

  • Slack J F, Herriman N, Barnes R G, Plimer I R (1984) Stratiform tourmalinites in metamorphic terranes and their geologic significance. Geology 12: 713–716

    Article  Google Scholar 

  • Smithies R H, Pirajno F (1988) Comments on the paper by I Plimer: The association of tourmalinite with stratiform scheelite deposits. Mineral Depos 23: 313–314

    Google Scholar 

  • Spooner ETC, Fyfe W S (1973) Subseafloor metamorphism, heat and mass transfer. Contrib Mineral Petrol 42: 287–304

    Article  Google Scholar 

  • Stanton R L (1972) Ore petrology. McGraw-Hill, New York, 713 pp

    Google Scholar 

  • Stanton R L (1982) An alternative to the Barrovian interpretation? Proc Australas Inst Min Metall 282: 11–32

    Google Scholar 

  • Stanton R L (1983) The direct derivation of sillimanite from a kaolinitic precursor: evidence from the Geco Mine, Manitouwadge, Ontario. Econ Geol 78: 422–437

    Article  Google Scholar 

  • Stanton R L (1989) The precursor principle and the possible significance of stratiform ores and related chemical sediments in the elucidation of processes of regional metamorphic mineral formation. Phil Trans R Soc London A 328: 529–646

    Article  Google Scholar 

  • Taylor H P (1971) Oxygen isotope evidence for large-scale interaction between meteoric ground waters and Tertiary granodiorite intrusions, western Cascade Range, Oregon. J Geophys Res 76: 7855–7874

    Article  Google Scholar 

  • Taylor H P (1974) The application of oxygen and hydrogen isotope studies to problems of hydrothermal alteration and ore deposition. Econ Geol 69: 843–883

    Article  Google Scholar 

  • Taylor R P, Fryer B J (1980) Multiple-stage hydrothermal alteration in porphyry copper systems in northern Turkey: the temporal interplay of potassic, propylitic, and phyllic fluids. Can J Earth Sei 17: 901–926

    Article  Google Scholar 

  • Taylor R P, Fryer B J (1982) Rare earth element geochemistry as an aid to interpreting hydrothermal ore deposits. In: Evans A M (ed) Mineralisation associated with acid magmatism. John Wiley & Sons, New York, pp 357–365

    Google Scholar 

  • Taylor R P, Fryer B J (1983) Rare earth element lithogeochemistry of granitoid mineral deposits. CIM Bull 76: 74–84

    Google Scholar 

  • Turner F J, Verhoogen J (1960) Igneous and metamorphic petrology. McGraw-Hill, New York, 693 pp

    Google Scholar 

  • Verwoerd W J (1966) Fenitisation of basic ignoeus rocks. In: Tuttle D F, Gittens J (eds) Carbonatites. Wiley Interscience, Amsterdam, New York, pp 295–308

    Google Scholar 

  • Whitney G, Abrams M J, Goetz A F H (1983) Mineral discrimination using a portable ratio-determining radiometer. Econ Geol 78: 688–698

    Article  Google Scholar 

  • Wonder T D, Spry P G, Windom K E (1988) Geochemistry and origin of manganese rich rocks related to iron-formation and sulfide deposits, Western Georgia. Econ Geol 83: 1070–1081

    Article  Google Scholar 

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Pirajno, F. (1992). Hydrothermal Alteration. In: Hydrothermal Mineral Deposits. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75671-9_5

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  • DOI: https://doi.org/10.1007/978-3-642-75671-9_5

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