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Natural and Magnetic Circular Dichroism Spectroscopies

  • A. J. Thomson

Abstract

Circular dichroism (Δε) is defined as the difference between the molar absorption coefficients for left (εL) and right (εR) circularly polarised light. A circular dichroism (CD) spectrum, consisting of a plot of Δε against wavelength or frequency, can therefore be observed only within absorption bands. CD generally arises from electronic transitions, although recently CD within vibrational bands has been measured. The two forms of CD spectroscopy to be discussed here are natural and magnetically induced.

Keywords

Electron Paramagnetic Resonance Circular Dichroism Circular Dichroism Spectrum Magnetic Dipole Moment Magnetic Circular Dichroism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Moscowitz A (1961) Tetrahedron 13: 48CrossRefGoogle Scholar
  2. 2.
    Kuhn W (1930) Trans. Far. Soc. 46: 293CrossRefGoogle Scholar
  3. 3.
    Weiss U, Ziffer H, Charney E (1965) Tetrahedron 21: 3105CrossRefGoogle Scholar
  4. 4.
    Charney E (1965) Tetrahedron 21: 3127CrossRefGoogle Scholar
  5. 5.
    Snätzke G (1979) Angew. Chem. Int. Ed. Engl. 18: 363CrossRefGoogle Scholar
  6. 6.
    Moffitt W, Woodward RB, Moscowitz A, Klyne W, Djerassi C (1961) J. Amer. Chem. Soc. 80:4013CrossRefGoogle Scholar
  7. 7.
    Mason SF (1963) Quart. Rev. 17: 20CrossRefGoogle Scholar
  8. 8.
    Harada N, Lai Chen S-M, Nakanishi K (1975) J. Amer. Chem. Soc. 97: 5354; Koreeda M, Harada N, Nakanishi K (1974) J. Amer. Chem. Soc. 95: 266CrossRefGoogle Scholar
  9. 9.
    Kriebel AN, Albrecht AC (1976) J. Chem. Phys. 65: 4575CrossRefGoogle Scholar
  10. 10.
    Moffitt W (1956) J. Chem. Phys. 25: 467CrossRefGoogle Scholar
  11. 11.
    Compton LA, Johnson WC (1986) Anal. Biochem. 155: 155CrossRefGoogle Scholar
  12. 12.
    Osborne GO, Cheng JC, Stephens PJ (1973) Rev. Sci. Inst. 44: 10CrossRefGoogle Scholar
  13. 13.
    Nafie LA, Keiderling TA, Stephens PJ (1976) J. Amer. Chem. Soc. 98: 2715CrossRefGoogle Scholar
  14. 14.
    Annamalai A, Keiderling TA (1984) J. Amer. Chem.Soc. 106: 6254CrossRefGoogle Scholar
  15. 15.
    Stephens PJ, Lowe MA (1985) Ann. Rev. Phys. Chem. 36: 213CrossRefGoogle Scholar
  16. 16.
    Nafie LA, Diem M (1979) Acc. Chem. Res. 12: 296CrossRefGoogle Scholar
  17. 17.
    Hug W, Surbeck H (1979) Chem. Phys. Lett. 60: 186CrossRefGoogle Scholar
  18. 18.
    Barron LD (1978) Tetrahedron 34: 607CrossRefGoogle Scholar
  19. 19.
    Barron LD (1977) J. Chem. Soc., Perkin II: 1074Google Scholar
  20. 20.
    Piepho S, Schatz PN (1983) Group theory in spectroscopy, Wiley, New YorkGoogle Scholar
  21. 21.
    Schatz PN, McCaffery AJ (1969) Quart. Rev. 23: 552CrossRefGoogle Scholar
  22. 22.
    Stephens PJ (1976) Adv. Chem. Phys. 35: 197CrossRefGoogle Scholar
  23. 23.
    Thomson AJ, Johnson MK (1980) Biochem. J. 191: 411Google Scholar
  24. 24.
    Wikström M, Krab K, Saraste M (1981) ‘Cytochrome c oxidase. A synthesis’, Academic, LondonGoogle Scholar
  25. 25.
    Thomson AJ, Eglinton DG, Hill BC, Greenwood C (1982) Biochem. J. 207: 167Google Scholar
  26. 26.
    Barrett CP, Peterson J, Greenwood C, Thomson AJ (1986) J. Amer. Chem. Soc., 108: 3170CrossRefGoogle Scholar

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© Springer-Verlag Berlin Heidelberg 1990

Authors and Affiliations

  • A. J. Thomson

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