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Structural Properties and Phase Transitions

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Graphite Intercalation Compounds I

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 14))

Abstract

In this chapter we review the subject of structure and phase transitions in the graphite intercalation compounds (GICs). Results on both donor and acceptor compounds are covered, for both liquid and solid states, and a range of structural phenomena are treated. This discussion of structure serves two purposes. Firstly, we are interested in structure per se and the GICs offer an extraordinary abundance of interesting phenomena. This abundance comes about through the interplay between intercalant-intercalant forces and graphite-intercalant forces, which ultimately are responsible for the intercalation process. Depending in detail upon these competing interactions, which are naturally sensitive to the choice of intercalant, a great variety of structural effects appear, ranging from altered host stackings to Daumas-Herold domains and staging and including host-modulated two-dimensional (2d) incommensurate liquids which freeze to incommensurate solids for which domain-discommensuration states have been derived. In fact, it may be said that the GICs, by providing a sequential stacking of intercalant layers, have substantially enhanced our understanding of structure and phase transitions in two dimensions.

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Authors
  1. Simon C. Moss
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  2. Roger Moret
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Editors and Affiliations

  1. Loomis Laboratory of Physics, University of Illinois at Urbana-Champaign, 1110 West Green Street, Urbana, IL, 61801, USA

    Hartmut Zabel

  2. Fakultät für Physik und Astronomie, Ruhr-Universitä Bochum, Universitätsstrasse 150, D-4630, Bochum 1, Fed. Rep. of Germany

    Hartmut Zabel

  3. NEC Research Institute, Inc., 4 Independence Way, Princeton, NJ, 08540, USA

    Stuart Solin Ph.D.

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Moss, S.C., Moret, R. (1990). Structural Properties and Phase Transitions. In: Zabel, H., Solin, S. (eds) Graphite Intercalation Compounds I. Springer Series in Materials Science, vol 14. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75270-4_2

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