UV-visible and Raman investigations of matrix isolated adducts between metal vapors of chromium and benzene: selective photoirradiations effects

  • M. Dalibart
  • J. Derouault
Conference paper

Abstract

The UV-visible absorption and the Raman spectra of chromium vapors trapped either in Ar-benzene mixtures or in neat benzene have been investigated. The data give evidence for the formation of the well-known dibenzene chromium sandwich complex but show also the formation of benzene complexes with the dimer Cr2 and with the cluster Cr3 photoirradiations effects have been studied.

PACS

78.00 

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References

  1. 1.
    Dalibart, M., Derouault, J., Labarrere, H., Tranquille, M.: J. Mol. Struct. 174, 17 (1988).ADSCrossRefGoogle Scholar
  2. 2.
    Tranquille, M.: Imag. Chimie 36, 18 (1980).Google Scholar
  3. 3.
    Pellin, M.J., Gruen, D.M.: J. Chem. Phys. 79, 5887 (1983).ADSCrossRefGoogle Scholar
  4. 4.
    Dalibart, M., Spectra 2000. 116, 69 (1986).Google Scholar
  5. 5.
    Dilella, D.P., Limm, W., Lipson, R.H., Moskovits, M., Taylor, K.V.: J. Chem. Phys. 77, 5263 (1982).ADSCrossRefGoogle Scholar
  6. 6.
    Klotzbucher, W.E., Ozin, G.A.: J. Am. Chem. Soc. 100, 2262 (1978).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 1989

Authors and Affiliations

  • M. Dalibart
    • 1
  • J. Derouault
    • 1
  1. 1.L.S.M.C. (U.A. 124), Université de Bordeaux ITalence-CedexFrance

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