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Small Particles and Inorganic Clusters pp 451–452Cite as

NMR of metal-core bonded 31P in polynuclear metal cluster compounds

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Abstract

In this paper we present measurements of nuclear relaxation times of 31P in the polynuclear cluster compounds Au55(PPh3)12Cl6 and Ru55(P(t-Bu)3)12Cl20. Above 15 K the data can be described as a Korringa process, while below 15 K the relaxation time appears to be thermally activated.

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References

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Author information

Authors and Affiliations

  1. Kamerlingh Onnes Laboratorium, Rijksuniversiteit Leiden, Postbus 9506, NL-2300, RA Leiden, The Netherlands

    M. P. J. van Staveren, H. B. Brom & L. J. de Jongh

  2. Institut fur Anorganische Chemie, Universität Essen, Universitätsstrasse 5-7, D-4300, Essen 1, Federal Republic of Germany

    G. Schmid

Authors
  1. M. P. J. van Staveren
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  2. H. B. Brom
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  3. L. J. de Jongh
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  4. G. Schmid
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Editor information

Editors and Affiliations

  1. Campus de Luminy, Case 913, CRMC2-CNRS, F-13288, Marseille Cedex 9, France

    Claude Chapon

  2. Laboratoire de Microscopie et Diffraction Electroniques, Faculté des Sciences et Techniques, rue Henri Poincaré, F-13387, Marseille Cedex 13, France

    Marcel F. Gillet  & Claude R. Henry  & 

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© 1989 Springer-Verlag

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van Staveren, M.P.J., Brom, H.B., de Jongh, L.J., Schmid, G. (1989). NMR of metal-core bonded 31P in polynuclear metal cluster compounds. In: Chapon, C., Gillet, M.F., Henry, C.R. (eds) Small Particles and Inorganic Clusters. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74913-1_102

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  • DOI: https://doi.org/10.1007/978-3-642-74913-1_102

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-74915-5

  • Online ISBN: 978-3-642-74913-1

  • eBook Packages: Springer Book Archive

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