Abstract
The term “isotope effect” in NMR spectroscopy refers to changes of NMR spectral parameters that may arise due to isotopic substitution (mX/nX) of element X. Molecules AmX and AnX, differing in isotopes of element X, with A being an invariable part of the molecules are called isotopomers. Thus, isotope effects may be defined as:
where θ is the measured spectral characteristics.
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Sergeyev, N.M. (1990). Isotope Effects on Spin-Spin Coupling Constants: Experimental Evidence. In: Isotope Effects in NMR Spectroscopy. NMR Basic Principles and Progress, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74835-6_2
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