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Chemical Models for Deuterium Isotope Effects in 13C- and 19F-NMR

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Isotope Effects in NMR Spectroscopy

Part of the book series: NMR Basic Principles and Progress ((NMR,volume 22))

Abstract

The research on isotope effects in organic chemistry is based on the vibrational theory [1]. Kinetic isotope effects in chemical reactions and equilibrium isotope effects have been dealt with on the basic assumption that the only important difference between isotopes is their mass and any effects from isotopic substitution ultimately should be traced back to this difference. Thus, within the Born-Oppenheimer approximation the electronic potential of a C–D bond is believed to be identical with the potential of a C–H bond. Isotope effects therefore are thought to stem from the anharmonicity of this potential and the different zero point energy of the heavier isotope within this potential.

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  1. Fachbereich Chemie, Universität Marburg, Hans Meerwein Straße, D-3550, Marburg, Germany

    S. Berger

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  1. S. Berger
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© 1990 Springer-Verlag, Berlin Heidelberg

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Berger, S. (1990). Chemical Models for Deuterium Isotope Effects in 13C- and 19F-NMR. In: Isotope Effects in NMR Spectroscopy. NMR Basic Principles and Progress, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74835-6_1

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  • DOI: https://doi.org/10.1007/978-3-642-74835-6_1

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-74837-0

  • Online ISBN: 978-3-642-74835-6

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