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Deprotonation and Alkylation of 1,3-Indandiones in a Water/N-Heptane/N-Octyl-Phenyl-Pentaoxyethylene Microemulsion

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Reactions in Compartmentalized Liquids

Abstract

Investigations are reported concerning the deprotonation of 1,3-indandione and 2-benzyl- 1,3-indandione and the alkylation of these compounds by benzylbromide. Both reactions are performed in a microemulsion and rate and equilibrium constants are determined. In order to discuss the results, deprotonation and alkylation are also studied in aqueous solution and polar organic solvents, respectively.

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© 1989 Springer-Verlag Berlin Heidelberg

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Schomäcker, R., Stickdorn, K., Knoche, W. (1989). Deprotonation and Alkylation of 1,3-Indandiones in a Water/N-Heptane/N-Octyl-Phenyl-Pentaoxyethylene Microemulsion. In: Knoche, W., Schomäcker, R. (eds) Reactions in Compartmentalized Liquids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74787-8_4

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  • DOI: https://doi.org/10.1007/978-3-642-74787-8_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-51188-5

  • Online ISBN: 978-3-642-74787-8

  • eBook Packages: Springer Book Archive

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