Kinetics and Mechanism of the Oxidation Reaction of Thioethers by Cerium(IV) Ammonium Nitrate

  • E. Baciocchi
  • D. Intini
  • C. Rol
Conference paper

Abstract

One electron oxidation of organic sulfides is certainly an important process particularly for the role that it may have in several biochemical transformations. In spite of this, detailed studies on chemically induced one electron transfer reactions of thioethers are very scarce (1).

Keywords

Sulfide Cerium Benzyl Sulfoxide AcOH 

References

  1. 1.
    Riley DP, Smith MR, Correa PE (1988) J Am Chem Soc 110:177; Gilmore JR, Mellor JM (1971) Tetrahedron Lett 3977; Watanabe Y, Iyanagi T, Oae S (1980) Tetrahedron Lett 3685; Srinivasan C, Chellamani A, Rajagopal S (1985) J Org Chem 50:1201CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • E. Baciocchi
    • 1
  • D. Intini
    • 2
  • C. Rol
    • 2
  1. 1.Dipartimento di ChimicaUniversità “La Sapienza”RomaItaly
  2. 2.Dipartimento di ChimicaUniversità di PerugiaPerugiaItaly

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