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The Cation-Radical of a Hindered Quinone Diazide

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Organic Free Radicals

Abstract

The anodic oxidation of 4-diazo-2,6-di-tert-butylcyclohexa-2,5-dienone at −88°C produces a cation-radical that has been shown by ESR and AMI MO calculations to have a π-radical structure similar to that of phenoxy radicals but quite in contrast to the σ/π-radical nature of simple diazoalkane cation radicals.

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References

  1. Denny DB, Newman NF (1967) J Am Chem Soc 89:4692

    Article  Google Scholar 

  2. Bethell D, Handoo KL, Fairhurst SA, Sutcliffe LH (1979) J Chem Soc, Perkin II 707

    Google Scholar 

  3. Winter W, Moosmayer A, Rieker A (1982) Z Naturforsch B 37:1623

    Google Scholar 

  4. Ishiguro K, Sawaki Y, Izuoka A, Sugawara T, Iwamura H (1987) J Am Chem Soc 109:2530

    Article  CAS  Google Scholar 

  5. Nikiforov GA, Plekhanova LG, De Jonge K, Ershov VV (1978) Izv Akad Nauk, Ser Khim 2752

    Google Scholar 

  6. Rieker A (1961) Thesis University of Tübingen

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Author information

Authors and Affiliations

  1. Institute for Molecular Science, Okazaki, 444, Japan

    H. Iwamura, A. Izuoka, T. Kohzuma, K. Ishiguro, Y. Sawaki, I. Mitulidis & A. Rieker

  2. Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya, Japan

    H. Iwamura, A. Izuoka, T. Kohzuma, K. Ishiguro, Y. Sawaki, I. Mitulidis & A. Rieker

  3. Institute for Organic Chemistry, University of Tübingen, 7400, Tübingen, Germany

    H. Iwamura, A. Izuoka, T. Kohzuma, K. Ishiguro, Y. Sawaki, I. Mitulidis & A. Rieker

Authors
  1. H. Iwamura
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  2. A. Izuoka
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  3. T. Kohzuma
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  4. K. Ishiguro
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  5. Y. Sawaki
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  6. I. Mitulidis
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  7. A. Rieker
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Editor information

Editors and Affiliations

  1. Physikalisch-Chemisches Institut, Universität Zürich, Winterthurerstraße 190, 8057, Zürich, Switzerland

    Hanns Fischer

  2. Organisch-Chemisches Institut, Universität Zürich, Winterthurerstraße 190, 8057, Zürich, Switzerland

    Heinz Heimgartner

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© 1988 Springer-Verlag Berlin Heidelberg

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Iwamura, H. et al. (1988). The Cation-Radical of a Hindered Quinone Diazide. In: Fischer, H., Heimgartner, H. (eds) Organic Free Radicals. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73963-7_81

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  • DOI: https://doi.org/10.1007/978-3-642-73963-7_81

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-50129-9

  • Online ISBN: 978-3-642-73963-7

  • eBook Packages: Springer Book Archive

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