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The Cation-Radical of a Hindered Quinone Diazide

  • H. Iwamura
  • A. Izuoka
  • T. Kohzuma
  • K. Ishiguro
  • Y. Sawaki
  • I. Mitulidis
  • A. Rieker
Conference paper

Abstract

The anodic oxidation of 4-diazo-2,6-di-tert-butylcyclohexa-2,5-dienone at −88°C produces a cation-radical that has been shown by ESR and AMI MO calculations to have a π-radical structure similar to that of phenoxy radicals but quite in contrast to the σ/π-radical nature of simple diazoalkane cation radicals.

Keywords

Cation Radical Anodic Oxidation Cyano Group Molecular Plane Phenoxy Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

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    Winter W, Moosmayer A, Rieker A (1982) Z Naturforsch B 37:1623Google Scholar
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    Ishiguro K, Sawaki Y, Izuoka A, Sugawara T, Iwamura H (1987) J Am Chem Soc 109:2530CrossRefGoogle Scholar
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    Nikiforov GA, Plekhanova LG, De Jonge K, Ershov VV (1978) Izv Akad Nauk, Ser Khim 2752Google Scholar
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    Rieker A (1961) Thesis University of TübingenGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • H. Iwamura
    • 1
    • 2
    • 3
  • A. Izuoka
    • 1
    • 2
    • 3
  • T. Kohzuma
    • 1
    • 2
    • 3
  • K. Ishiguro
    • 1
    • 2
    • 3
  • Y. Sawaki
    • 1
    • 2
    • 3
  • I. Mitulidis
    • 1
    • 2
    • 3
  • A. Rieker
    • 1
    • 2
    • 3
  1. 1.Institute for Molecular ScienceOkazakiJapan
  2. 2.Faculty of EngineeringNagoya UniversityChikusa-kuJapan
  3. 3.Institute for Organic ChemistryUniversity of TübingenTübingenGermany

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