Stereochemical Effect on Intramolecular Substitutions in Induced Decomposition of Allylic Percarbonates
Free radical additions of methylne chloride to unsaturated O,O-t-butyl O-allylic percarbonates showed the existence of a stereochemical effect on intramolecular substitution at the O-O bond of the percarbonate.
KeywordsTransition State Hydrogen Atom Double Bond Methylene Chloride Mechanistic Study
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