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Stereochemical Effect on Intramolecular Substitutions in Induced Decomposition of Allylic Percarbonates

  • X. Lubeigt
  • E. Montaudon
  • B. Maillard
Conference paper

Abstract

Free radical additions of methylne chloride to unsaturated O,O-t-butyl O-allylic percarbonates showed the existence of a stereochemical effect on intramolecular substitution at the O-O bond of the percarbonate.

Keywords

Transition State Hydrogen Atom Double Bond Methylene Chloride Mechanistic Study 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature

  1. (1).
    M.J. Bourgeois, E. Montaudon, B. Maillard, Bull. Soc. Chim. Belg., 94, 255, (1988) and precedent papers of this series.Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • X. Lubeigt
    • 1
  • E. Montaudon
    • 1
  • B. Maillard
    • 1
  1. 1.Université de Bordeaux ITalence-CédexFrance

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