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β-Fragmentation of Alkyl Radicals. Polar and Steric Effects

  • K. Klenke
  • J. O. Metzger
Conference paper

Abstract

Radical fragmentation is the reverse of radical addition. The importance of polar and steric effects to addition reactions is well known . We report here the influence of polar and steric effects on the selectivity of β-scission of alkyl radicals.

Keywords

Carbon Atom Alkyl Radical High Selectivity Relative Rate Reactive Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    J.M. Tedder (1982) Angew. Chem. 94, 433; Angew. Chem. Int. Ed. Engl. 21, 401; B. Giese (1983) Angew. Chem. 95, 771; Angew. Chem. Int. Ed. Engl. 22, 753CrossRefGoogle Scholar
  2. 2.
    J. Hartmanns, K. Klenke und J.O. Metzger (1986) Chem. Ber. 119, 488CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • K. Klenke
    • 1
  • J. O. Metzger
    • 1
  1. 1.Department of ChemistryUniversity of OldenburgOldenburgGermany

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