Cidnp in the Reactions of Photooxidation of Benzylic Acid and Phenols Sensitized by Uranyl Ion

  • A. L. Buchachenko
  • I. V. Khudyakov
  • E. S. Klimtchuk
  • L. A. Margulis
Conference paper

Abstract

A search of reversible steps in photochemical reactions of uranyl ion seems to be an important problem of photochemistry and magnetochemistry. The present poster is devoted to the CIDNP study in the reactions of photoexcited uranyl ions with phenols (∅OH) and benzylic acid in methanol-d4. The following OOH have been used: p-cra-sol , 2,6-di-tert-butylphenol , 2,6-di-tert-buti1-4-methylphenol , 2,6-di-tert-butyl-4-ethyl phenol.

Keywords

Phenol Cage Photolysis Uranyl Photooxidation 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • A. L. Buchachenko
    • 1
    • 2
  • I. V. Khudyakov
    • 1
    • 2
  • E. S. Klimtchuk
    • 1
    • 2
  • L. A. Margulis
    • 1
    • 2
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscowUSSR
  2. 2.A.Z.Yankelevich Karpov Institute of Physical ChemistryMoscowUSSR

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