Radical Cations From Alkyl Iodides and 1,n-Halogen(Alkylthio)Alkanes in Solution

  • K. D. Asmus
  • E. Anklam
  • H. Mohan

Abstract

Radical cations of the general type (-I∴I-)+, (=S∴I-)+, (=S∴Br-)+, and (=S∴S=)+ with optical absorptions in the UV/VIS are formed upon one-electron oxidation of alkyl iodides and 1 ,n-halogen(alkylthio)alkanes.

Keywords

Sulfide Iodine Adduct Iodide Alkane 

References

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    Mohan H, Asmus K-D (1987) J Chem Soc Perkin Trans 2 :1795Google Scholar
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    Mohan H, Asmus K-D (1987) J Amer Chem Soc 109:4745CrossRefGoogle Scholar
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    Mohan H, Asmus K-D (1988) J Phys Chem 92:118CrossRefGoogle Scholar
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    Anklam E, Mohan H, Asmus K-D (1987) Helv Chim Acta 70:2110CrossRefGoogle Scholar
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    Anklam E, Mohan H, Asmus K-D (1988) J Chem Soc Perkin Trans 2 :000Google Scholar
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    Asmus K-D (1979) Acc Chem Res 12:436CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • K. D. Asmus
    • 1
  • E. Anklam
    • 1
  • H. Mohan
    • 1
  1. 1.Hahn-Meitner-Institut BerlinBereich StrahlenchemieBerlin 39Germany

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