Cyclopentane Ring Formation in the Cycloaddition Reactions of 3-Butenyl Radical on the Electron-Deficinet Olefins

  • Živorad Čeković
  • Radomir Saičić
Conference paper

Abstract

By decomposition of thiohydroxamic esters of 4-pentenoic acid in the presence of symmetrical electron-deficient olefinic compounds, intermolecular and intramolecular radical additions takes place and polysubstituted cyclopentane derivatives were obtained.

Keywords

Ethyl Benzene Toluene Cyclopentane 

References

  1. 1).
    M. Ramaiah, Tetrahedron, 43, 3541 (1987) and references thereinCrossRefGoogle Scholar
  2. 2).
    G. Stork and P. M. Sher, J. Am. Chem. Soc., 108, 303 (1986)CrossRefGoogle Scholar
  3. 3).
    Ž. Čeković and R. Saičić, Tetrahedron Letters, 27, 5893 (1986).CrossRefGoogle Scholar
  4. 4).
    Ž. Čeković and D. Ilijev, Tetrahedron Letters, 29, 1441 (1988)CrossRefGoogle Scholar
  5. 5).
    D. H. R. Barton and G. Kretzschmar, Tetrahedron Letters, 5889 (1983).Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • Živorad Čeković
    • 1
  • Radomir Saičić
    • 1
  1. 1.Department of Chemistry, Faculty of SciencesUniversity of BelgradeBelgradeYugoslavia

Personalised recommendations