Abstract
The main characteristic of a metal is the presence of free electrons (the so-called electron gas), which account for the high electroconductivity of metals. In the transition metals the d electrons are more localized than the sp electrons, the latter therefore being mainly responsible for the conduction of electricity. However, the extremely high differences in the electroconductivity (and its temperature dependence) of metals and oxides have little effect on the chemisorptive and catalytic properties of their surface. The catalytic and adsorptive properties of both the metals and the oxides depend mainly on the d electrons, which exhibit a high degree of localization.
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Kiselev, V.F., Krylov, O.V. (1989). The Surface of the Transition Metals. In: Adsorption and Catalysis on Transition Metals and Their Oxides. Springer Series in Surface Sciences, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73887-6_5
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