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Processes of Separation and Transformation in C4-Chemistry

  • Chapter
C4-Hydrocarbons and Derivatives

Abstract

Pure butadiene cannot be separated from the C4-cut by distillation. Both 1,3- butadiene and trans-2-butene form azeotropes with n-butane; vinylacetylene likewise forms azeotropes with cis- or trans-2-butenes, differing only slightly in boiling point from butadiene. Finally, the boiling points of i-butene and 1-butene are so near that their distillative separation is uneconomic (Table 3.1).

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  1. Institut für Technische Chemie FB Physikalische und Angewandte Chemie, Technische Universität Berlin, Straße des 17. Juni 135, D-1000, Berlin 12, Germany

    Prof. Dr.-Ing. Joachim Schulze

  2. Deutsche Shell Chemie GmbH, Kölner Str. 6, D-6236, Eschborn, Germany

    Dr.-Ing. Malte Homann

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  1. Prof. Dr.-Ing. Joachim Schulze
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Schulze, J., Homann, M. (1989). Processes of Separation and Transformation in C4-Chemistry. In: C4-Hydrocarbons and Derivatives. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73858-6_4

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