Abstract
Coincidence studies between Auger electrons and ions produced in the decay of a core hole excited state in free molecules reveal the individual pathways of soft x-ray induced fragmentation processes. We are able to identify the electronic configuration leading to stable or unstable ionic states. Measuring the kinetic energy of the ions, we also get data about the potential energy curves of the electronic states populated in the Auger decay of the core hole.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
W. Eberhardt, T. K. Sham, R. Carr, S. Krummacher, M. Strongin, S. L. Weng, D. Wesner, Phys. Rev. Lett. 50, 1038 (1983).
W. Eberhardt, C. T. Chen, W. K. Ford, E. W. Plummer, H. R. Moser, in “DIET II,” Springer Series in Surf. Sci. Vol. 4, ed. by W. Brenig and D. Menzel, ( Springer, Berlin 1985 ) p. 50.
W. Eberhardt, E. W. Plummer, In Whan Lyo, R. Reininger, R. Carr, W. K. Ford, D. Sondericker, Austral. J. of Physics 39, 633 (1986).
One exception to this has been observed to date. In HBr the creation of a Br 3d core hole was shown to directly lead to a dissociative state; P. Morin and I. Nenner, Phys. Rev. Lett. 56. 1913 (1986).
W. Eberhardt, E. W. Plummer, I. W. Lyo, R. Carr, W. K. Ford, Phys. Rev. Lett. 58, 207 (1987).
J. Eland in Electron Spectroscopy Vol. 3, ed. by C.R. Brundle and A. D. Baker, ( Academic Press, London 1979 ) p. 231.
G. R. Wight, M. J. van der Wiel, C. E. Brion, J. Phys. B 9, 675 (1976).
P. Millie, I. Nenner, P. Archirel, P. Lablanquie, P. Fournier, J. H. D. Eland, J. Chem. Phys. 84, 1259 (1986).
W. Eberhardt, J. Stohr, C. Troxel, Jr., J. Feldhaus, E. W. Plummer, F. Sette, Rev. Sci. Instrum. 55, 354 (1984).
W. Eberhardt, E. W. Plummer, C. T. Chen, R. Carr, W. K. Ford, Nucl. Instrum. and Methods A246, 825 (1986).
W. Eberhardt, J. Stohr, J. Feldhaus, E. W. Plummer, F. Sette, Phys. Rev. Lett. 51, 2370 (1983).
F. R. Gilmore, J. Quant. Spectr. Rad. Transfer 5, 369 (1965).
A. L. Roche, H. Lefebvre-Brion, Chem. Phys. Lett. 32, 155 (1975).
H. Agren, J. Chem. Phys. 75, 1267 (1981).
P. Erman, Physica Scripta 14, 51 (1976).
J. L. Gardner, J. A. R. Samson, J. Chem. Phys. 62, 1451 (1975).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1988 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Eberhardt, W., Murphy, R. (1988). Auger Electron-Ion Coincidence Studies on Free Molecules. In: Stulen, R.H., Knotek, M.L. (eds) Desorption Induced by Electronic Transitions DIET III. Springer Series in Surface Sciences , vol 13. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73728-2_3
Download citation
DOI: https://doi.org/10.1007/978-3-642-73728-2_3
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-73730-5
Online ISBN: 978-3-642-73728-2
eBook Packages: Springer Book Archive