Abstract
When graphite samples are exposed at elevated temperature to the vapor phase of either alkali metals or a variety of molecular species, they form compounds in which the normal sequence of stacked hexagonal graphite layers is regularly interrupted by layers of the (so-called) intercalated species. These graphite intercalation compounds, or GIC℉s /1,2/, thereby provide us with very interesting examples of two-dimensional (2D) systems of interacting particles in a periodic host lattice. The competing interactions in the GIC℉s that determine the structure and dynamics of the intercalated layer are a) the interatomic or intermolecular potential and b) the host-intercalant potential. There are also, of course, the interlayer interactions responsible for the regular sequencing of the intercalated species and these are repulsive due both to coulombic and elastic effects /3/.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
S. A. Solin: Adv. Chem. Phys. 49, 455 (1982)
R. Moret: in Intercalation in Layered Materials, ed. by M. S. Dresselhaus, NATO AS I Series, Series B Physics 148, 185 (1986)
G. Kirczenow: Phys. Rev. Lett. 52, 437 (1984); Phys. Rev. B31, 5376 (1985)
G. S. Parry and D. E. Nixon: Nature 216, 909 (1967)
H. Zabel, S. C. Moss, N. Caswell and S. A. Solin, Phys. Rev. Lett. 42, 1552 (1979)
K. Ohshima, S. C. Moss and R. Clarke: Synth. Met. 12, 125 (1985)
R. Clarke, J. N. Gray, H. Homma and M. J. Winokur: Phys. Rev. Lett. 47, 1407 (1981)
Y. Yamada and I. Naiki: J. Phys. Soc. Japan 51, 2174 (1982)
M. Suzuki and H. Suematsu: J. Phys. Soc. Japan 52, 2761 (1983)
M. Suzuki: Phys. Rev. B33, 1386 (1986).
R. Clarke, N. Caswell, S. A. Solin and P. M. Horn: Phys. Rev. Lett 43, 2018 (1979)
H. Zabel, S. E. Hardcastle, D. A. Neumann, M. Suzuki and A. Magerl: Phys. Rev. Lett. 57, 2041 (1986)
E. D. Specht, M. Sutton, R. J. Birgeneau, D. E. Moncton and P. M. Horn: Phys. Rev. B30, 1589 (1984)
K. L. D’Amico, D. E. Moncton, E. D. Specht, R. J. Birgeneau, S. E. Nagler and P. M. Horn: Phys. Rev. Lett. 53, 2230 (1984)
S. K. Sinha: in Neutron Scattering, ed. by D. L. Price and K. Skold in the Series: “Methods of Experimental Physics”, Springer-Verlag, New York (1987), in press.
W. A. Kamitakahara and H. Zabel: Phys. Rev. B32, 7817 (1985)
H. Zabel, A. Magerl, A. J. Dianoux and J. J. Rush: Phys. Rev. Lett. 50, 2094 (1983)
G. S. Parry: Mater. Sci. Eng. 31, 99 (1977)
F. Rousseaux, R. Moret, D. Guerard, P. Lagrange and M. Lelaurain: Synth. Met. 12, 45 (1985)
M. Morf, S. C. Moss, Y. M. Jan and H. Zabel: Phys. Rev. B25, 1287 (1982)
M. J. Winokur and R. Clarke: Phys. Rev. Lett. 54, 811 (1985)
M. Plischke: Can. J. Phys. 59, 802 (1981)
M. Plischke and W. D. Leckie: Can. J. Phys. 60, 1139 (1982)
P. B. Visscher and L. M. Falicov: Phys. Rev. B3, 2541 (1971)
G. Reiter and S. C. Moss: Phys. Rev. B33, 7209 (1986)
S. C. Moss, G. Reiter, J. L. Robertson, C. Thompson, J. D. Fan and K. Ohshima: Phys. Rev. Lett. 57, 3191 (1986)
C. Thompson: Thesis for the Ph.D. degree, Department of Physics, University of Houston. May (1987); C. Thompsion and S. C. Moss, to be published
X. B. Kan, J. L. Robertson, S. C. Moss, K. Ohshima and C. J. Sparks; to be published
H. Zabel, Y. M. Jan and S. C. Moss: Physica 99B, 453 (1980)
J. D. Fan: Thesis for the Ph.D. degree, Department of Physics, University of Houston (in progress)
D. E. Nixon, K. M. Lester and B. C. Levene: J. Phys. C2, 2156 (1969)
C. Thompson, M. E. Mi senheimer and S. C. Moss: Acta Cryst (in press)
D. P. DiVincenzo and E. J. Meie: Phys. Rev. B32, 2538 (1985)
J. D. Fan, Omar A. Karim, G. Reiter and S. C. Moss: to be published
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1988 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Moss, S.C., Kan, X.B., Fan, J.D., Robertson, J.L., Reiter, G., Karim, O.A. (1988). Structure and Modeling of 2D Alkali Liquids in Graphite. In: LeSar, R., Bishop, A., Heffner, R. (eds) Competing Interactions and Microstructures: Statics and Dynamics. Springer Proceedings in Physics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73498-4_15
Download citation
DOI: https://doi.org/10.1007/978-3-642-73498-4_15
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-73500-4
Online ISBN: 978-3-642-73498-4
eBook Packages: Springer Book Archive