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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 27))

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Abstract

When graphite samples are exposed at elevated temperature to the vapor phase of either alkali metals or a variety of molecular species, they form compounds in which the normal sequence of stacked hexagonal graphite layers is regularly interrupted by layers of the (so-called) intercalated species. These graphite intercalation compounds, or GIC℉s /1,2/, thereby provide us with very interesting examples of two-dimensional (2D) systems of interacting particles in a periodic host lattice. The competing interactions in the GIC℉s that determine the structure and dynamics of the intercalated layer are a) the interatomic or intermolecular potential and b) the host-intercalant potential. There are also, of course, the interlayer interactions responsible for the regular sequencing of the intercalated species and these are repulsive due both to coulombic and elastic effects /3/.

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© 1988 Springer-Verlag Berlin Heidelberg

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Moss, S.C., Kan, X.B., Fan, J.D., Robertson, J.L., Reiter, G., Karim, O.A. (1988). Structure and Modeling of 2D Alkali Liquids in Graphite. In: LeSar, R., Bishop, A., Heffner, R. (eds) Competing Interactions and Microstructures: Statics and Dynamics. Springer Proceedings in Physics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73498-4_15

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  • DOI: https://doi.org/10.1007/978-3-642-73498-4_15

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