Reactions of Imidoselenium Compounds

  • Alain Krief
  • László Hevesi

Abstract

In 1976 Sharpless reported [592] that ß-pinene afforded the corresponding allylic amine when reacted in methylene chloride whith selenium diimides 63 and 64 (Schemes 250, 251) obtained from selenium tetrachloride and t-butyl amine (2 equiv.) or p-toluene sulfonamide (2 equiv.) respectively in the presence of an amine base (4 equiv.). Even better results have been observed [592] using reagent 65 (0.63 to 0.83 mol. equiv. around 20 °C. Scheme 250), although 64 and 65 should be structurally identical. Under these conditions side reactions leading to multiple allylic amination or to the corresponding diene are minimized [592].

Keywords

Selenium Alkyne Diene Hept Boride 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • Alain Krief
    • 1
  • László Hevesi
    • 1
  1. 1.Département de ChimieFacultés Universitaires Notre-Dame de la PaixNamurBelgium

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