Abstract
A method for the study of ionic hydration in aqueous solutions using infrared spectroscopy has recently been developed (Kristiansson 1984 a,b). The quantitative aspect of this method has been further developed, and concentration studies using Ni(C104)2 and Ni(BF4)2 have been performed (Kristiansson 1987). A relation between the spectra and the number of coordinated water molecules as well as reliable band parameters for the different hydration bands were obtained. In the present contribution we will discuss some results for NaC104, LiC104, Ca(C104)2 and Mg(C104)2 solutions.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Kristiansson O, Eriksson A, Lindgren J, (1984a) Hydration of ions in aqueous solutions studied by infrared spectroscopy. I. Method. Acta Chem. Scand. A38: 609–612
Kristiansson O,Lindgren J, (to be published). A quantitative infrared spectroscopic method for the study of the hydration of ions in aqueous solutions.
Enderby J E, (1983) Neutron scattering from ionic solutions. Ann. Rev. Phys. Chem. 34: 155–185.
Heinzinger K, (1985) Computer simulations of aqueous electrolyte solutions. Physica 131B: 196–216.
Berglund B,Lindgren J,Tegenfeldt J, (1978) On the correlation between deuteron quadrupole coupling constants, 0-H and 0-D stretching frequencies and hydrogen-bond distances in solid hydrates. J. Mol. Structure 43: 179–191
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Lindgren, J., Kristiansson, O., Paluszkiewicz, C. (1987). Infrared Studies of Ionic Hydration in Aqueous Solutions. In: Kleeberg, H. (eds) Interactions of Water in Ionic and Nonionic Hydrates. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72701-6_6
Download citation
DOI: https://doi.org/10.1007/978-3-642-72701-6_6
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-17846-0
Online ISBN: 978-3-642-72701-6
eBook Packages: Springer Book Archive