Abstract
In order to get information on the hydration of polyethylenoxid deri- vates PEO like 
or 
their saturated aqueous solutions in CCl4 were investigated. Tne total water content was determined by Karl Fischer-titration and the H2O-interactions were evaluated by infrared spectroscopy in the region of the OH-stretching vibrations as well as of the OH-combination vibration (antisymmetric stretch + bending). In these ternary solutions about 1 mol H2O/NP-10 and about 0.4 mol H2O/NP-1O-M form hydrogen bonds with the surfactants. The spectra indicate, that these differences may be due to the larger acceptor strength of the alkoholic OH compared to the ether-oxygen group of NP-10. The different possibilities of water — surfactant interactions will be discusssed.
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© 1987 Springer-Verlag Berlin Heidelberg
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Klein, D., Kleeberg, H., Luck, W.A.P. (1987). IR-Spectroscopic Studies on the Hydration of Polyglycolethers. In: Kleeberg, H. (eds) Interactions of Water in Ionic and Nonionic Hydrates. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72701-6_35
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DOI: https://doi.org/10.1007/978-3-642-72701-6_35
Publisher Name: Springer, Berlin, Heidelberg
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