Abstract
The oxidation of carbon monoxide on palladium surfaces comprises one of the most extensively studied model systems in heterogeneous catalysis. The reaction has been investigated on the low index crystal surfaces by a variety of experimental techniques, and it was found that the temperature dependence of the steady state reaction on Pd {111}, {110}, {210}, {100} and polycrystalline palladium shows almost no difference [1]. Because of this apparent insensitivity with respect to surface structure, it was concluded that the reaction is “structure-insensitive” and it is therefore widely regarded as the prime example of a heterogeneous catalytic reaction not dependent on surface topography.
Keywords
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
G. Ertl and J. Koch, Proc. 5th Int. Congr. Catalysis, Palm Beach, 1972, 969; G. Ertl, in “Chemistry and Physics of Solid Surfaces, Vol. 111, ed. R. Vanselow, W. England, CRC Press, Boca Raton, (1982).
T. Engel and G. Ertl, J. Chem. Phys. 69 (1978) 1267.
M. Wolf, J. öoschnick, J. Loboda-Cackovic, M. Grunze, W.N. Unertl and Ü.H. Block, Surf. Sci., in press.
S.M. Francis and N.V. Richardson, Phys. Rev. B 33 (1986) 662.
J. Goschnick, M. Wolf, M. Grunze, W.N. Unertl, J.H. Block and J. Loboda-Cackovic, Surf. Sci., (1986). Proceedings of ECOSS 8, Jülich (1986).
J. Goschnick, Dissertation, F.U. Berlin (1987).
H. Conrad, G. Ertl andü. Küppers, Surf. Sci. 76 (1978) 323.
D. Mukesh, W. Morton, C. N. Kenney and M.B. Catlip, Surf. Sci. 138 (1984) 237.
J. Koch, Ph.D. Thesis, T.U. Hannover, (1972).
H. Hopster, H. Ibach andG. Comsa,U. Catal., 46, (1977) 37.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Goschnick, J., Loboda-Cackovic, J., Block, J.H., Grunze, M. (1987). The Reaction of Carbon Monoxide with Chemisorbed Oxygen on Pd(110): An Example of a Structure-Sensitive Reaction. In: Grunze, M., Kreuzer, H.J. (eds) Kinetics of Interface Reactions. Springer Series in Surface Sciences, vol 8. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72675-0_22
Download citation
DOI: https://doi.org/10.1007/978-3-642-72675-0_22
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-72677-4
Online ISBN: 978-3-642-72675-0
eBook Packages: Springer Book Archive