Abstract
The two 3,7-disubstituted diquinanes 510 and 511 have been investigated by single crystal X-ray diffraction techniques and shown to possess the illustrated W conformation [224]. Nonbonded H----H distances of 1.754(4) and 1.713(3) Å have been measured by low-temperature neutron diffraction experiments for 512 and 513 [225]. At 2.921(4) Å, the distance between the pairs of double bonds in 514 is also quite short [226].
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Paquette, L.A., Doherty, A.M. (1987). Physical Data for, and Theoretical Analysis of, Polyquinanes. In: Polyquinane Chemistry. Reactivity and Structure Concepts in Organic Chemistry, vol 26. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72598-2_4
Download citation
DOI: https://doi.org/10.1007/978-3-642-72598-2_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-72600-2
Online ISBN: 978-3-642-72598-2
eBook Packages: Springer Book Archive