Abstract
The two 3,7-disubstituted diquinanes 510 and 511 have been investigated by single crystal X-ray diffraction techniques and shown to possess the illustrated W conformation [224]. Nonbonded H----H distances of 1.754(4) and 1.713(3) Å have been measured by low-temperature neutron diffraction experiments for 512 and 513 [225]. At 2.921(4) Å, the distance between the pairs of double bonds in 514 is also quite short [226].
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© 1987 Springer-Verlag Berlin Heidelberg
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Paquette, L.A., Doherty, A.M. (1987). Physical Data for, and Theoretical Analysis of, Polyquinanes. In: Polyquinane Chemistry. Reactivity and Structure Concepts in Organic Chemistry, vol 26. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72598-2_4
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DOI: https://doi.org/10.1007/978-3-642-72598-2_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-72600-2
Online ISBN: 978-3-642-72598-2
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