Abstract
The photochemical reaction dynamics of chlorine dioxide (OClO) are investigated using femtosecond pump-probe spectroscopy. It is found that the majority of the dynamics can be attributed to the formation and vibrational relaxation of OClO from geminate recombination of the primary ClO and O photofragments.
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Philpott, M.J., Hayes, S.C., Reid, P.J. (1998). Investigating the Photochemical Dynamics of Chlorine Dioxide in Water and Acetonitrile using Ultrafast Pump-Probe Spectroscopy. In: Ultrafast Phenomena XI. Springer Series in Chemical Physics, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72289-9_180
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