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Excitation Energy Dependence of the H/D Isotope Effect in the Geminate Recombination of Hydrated Electrons

  • Martin U. Sander
  • Mark S. Gudiksen
  • Klaus Luther
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 63)

Abstract

The probability for the geminate recombination of hydrated electrons was measured after two-photon excitation of liquid H2O and D2O at 10 eV two-photon energy. As compared to earlier results with an excitation energy of 8 eV, the H/D isotope effect on the recombination probability is reversed.

Keywords

Excitation Energy Isotope Effect Hydrated Electron Recombination Probability Geminate Recombination 
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Copyright information

© Springer-Verlag Berlin Heidelberg 1998

Authors and Affiliations

  • Martin U. Sander
    • 1
    • 2
  • Mark S. Gudiksen
    • 1
  • Klaus Luther
    • 1
    • 2
  1. 1.Institut für Physikalische ChemieUniversität GöttingenGöttingenGermany
  2. 2.Max-Planck-Institut für Biophysikalische ChemieGöttingenGermany

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