Excitation Energy Dependence of the H/D Isotope Effect in the Geminate Recombination of Hydrated Electrons
The probability for the geminate recombination of hydrated electrons was measured after two-photon excitation of liquid H2O and D2O at 10 eV two-photon energy. As compared to earlier results with an excitation energy of 8 eV, the H/D isotope effect on the recombination probability is reversed.
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