Femtosecond mid-infrared pump-probe spectroscopy of water and ice

  • Sander Woutersen
  • Uli Emmerichs
  • Huib J. Bakker
Conference paper
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 63)

Abstract

We have used femtosecond mid-infrared pump-probe spectroscopy on the OH-stretching mode of HDO dissolved in D2O to investigate both the orientational and vibrational dynamics of water and ice. The orientational data provide evidence for a two-component structure of liquid water. The vibrational lifetime of the OH-stretch mode shows a remarkable temperature dependence: in water it is twice as long as in ice, and is found to increase with temperature.

Keywords

Anisotropy 

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References

  1. 1.
    U. Emmerichs, S. Woutersen, and H. J. Bakker, J. Opt. Soc. Am. B 14, 1480 (1997).ADSCrossRefGoogle Scholar
  2. 2.
    S. Woutersen, U. Emmerichs, and H. J. Bakker, Science 278, 658 (1997).ADSCrossRefGoogle Scholar
  3. 3.
    S. Woutersen, U. Emmerichs, H.-K. Nienhuys, and H. J. Bakker, to appear in Phys. Rev. Lett. 81 (1998).Google Scholar
  4. 4.
    P. Moore, A. Tokmakoff, T. Keyes, and M. D. Fayer, J. Chem. Phys. 103, 3325 (1995).ADSCrossRefGoogle Scholar
  5. 5.
    A. Staib and J. T. Hynes, Chem. Phys. Lett. 204, 197 (1993).ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1998

Authors and Affiliations

  • Sander Woutersen
    • 1
  • Uli Emmerichs
    • 1
  • Huib J. Bakker
    • 1
  1. 1.FOM-Institute AmolfAmsterdamThe Netherlands

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