Abstract
Conical intersections of potential-energy surfaces have emerged as a central mechanistic concept in photochemistry. This paper discusses characteristic features of the ultrafast non-Born-Oppenheimer dynamics mediated by conical intersections as well as the real-time detection of these processes.
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References
J. von Neumann and E. Wigner, Physik. Z., 30, 467, 1929; E. Teller, J. Phys. Chem., 41, 109, 1937.
S. S. Xantheas, G. J. Atchity, S. T. Elbert, and K. Ruedenberg, J. Chem. Phys., 94, 8054, 1991; D. R. Yarkony, J. Chem. Phys., 100, 3639, 1994; F. Bernardi, S. De, M. Olivucci, and M. A. Robb, J. Am. Chem. Soc., 112, 1737, 1990; A. L. Sobolewski, C. Woywod, and W. Domcke, J. Chem. Phys., 98, 5627, 1993.
M. A. Robb, F. Bernardi, and M. Olivucci, Pure & Appi. Chem., 67, 783, 1995.
M. Klessinger and J. Michl, Excited States and Photochemistry of Organic Molecules, VCH, New York, 1995.
E. E. Nikitin, in Chemische Elementarprozesse, Ed. H. Hartmann, Springer, Berlin, p. 70, 1968.
H. Koppel, W. Domcke, and L. S. Cederbaum, Adv. Chem. Phys., 57, 59, 1984.
W. Domcke and G. Stock, Adv. Chem. Phys., 100, 1, 1997.
H. Koppel and W. Domcke, in Encyclopedia of Computational Chemistry, Ed. P. v. R. Schleyer, Wiley, New York, in press.
L. Seidner and W. Domcke, Chem. Phys., 186, 27, 1994; R. Schneider, W. Domcke, and H. Koppel, J. Chem. Phys., 92, 1045, 1990; U. Manthe and H. Koppel, J. Chem. Phys., 93, 345, 1658, 1990.
S. Mukamel, Principles of Nonlinear Optical Spectroscopy, Oxford UP, New York, 1995.
L. Seidner, G. Stock, and W. Domcke, J. Chem. Phys., 103, 3998, 1995.
B. Wolfseder, L. Seidner, G. Stock und W. Domcke, Chem. Phys., 217, 275, 1997.
G. Stock, J. Chem. Phys., 103, 10015, 1995.
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© 1998 Springer-Verlag Berlin Heidelberg
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Domcke, W., Seidner, L., Stock, G. (1998). Conical Intersections and Femtosecond Dynamics. In: Ultrafast Phenomena XI. Springer Series in Chemical Physics, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72289-9_147
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DOI: https://doi.org/10.1007/978-3-642-72289-9_147
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-72291-2
Online ISBN: 978-3-642-72289-9
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