Abstract
The dynamics of charge-transfer-to-solvent (CTTS) precursor states in I¯(D2O)n clusters are studied using anion femtosecond photoelectron spectroscopy. For the n=4 cluster, excitation of a dipole-bound state results in a simple decay by vibrational autodetachment. In the n=5 and n=6 clusters, the initially excited dipole-bound state undergoes solvent reorganization in order to stabilize the excess electron.
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Zanni, M.T., Lehr, L., Greenblatt, B.J., Weinkauf, R., Neumark, D.M. (1998). Dynamics of Charge-Transfer-to-Solvent Precursor States in I-(D2O)n Clusters. In: Ultrafast Phenomena XI. Springer Series in Chemical Physics, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72289-9_143
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DOI: https://doi.org/10.1007/978-3-642-72289-9_143
Publisher Name: Springer, Berlin, Heidelberg
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