Abstract
Ultrafast dynamics of a quasi-one-dimensional halogen bridged mixed valence metal complex (HMMC) is studied by the pump-probe spectroscopy extending over 0.5–2.5 eV. Just after the photo-excitation, non-thermal self-trapped excitions (STE’s) are generated as well as charged solitons. The non-thermal STE’s have two relaxation channels to thermal STE’s and spin solitons.
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© 1998 Springer-Verlag Berlin Heidelberg
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Sugita, A., Yamashita, M., Kobayashi, T. (1998). Ultrafast broadband (0.5–2.5eV) absorption spectroscopy of a one-dimensional mixed-valence metal complex. In: Ultrafast Phenomena XI. Springer Series in Chemical Physics, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72289-9_103
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DOI: https://doi.org/10.1007/978-3-642-72289-9_103
Publisher Name: Springer, Berlin, Heidelberg
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