Abstract
In the first theoretical approach to the interface between two immiscible electrolyte solutions (ITIES) by Verwey and Messen [1], the interface was represented by a diffuse double layer, i.e. one phase containing an excess of the positive space charge and the other phase an equal excess of the negative space charge. The space charge regions have been treated by the Gouy-Chapman theory [2, 3]. Gavach et al. [4] have suggested that the two space charge regions are separated by an inner or compact layer of oriented solvent molecules — a modified Verwey-Niessen (MVN) model. The inner layer can be either free of ions or the ions are located in the inner layer as specifically adsorbed particles. Boguslavsky et al. [5,6] and Joos and Vanden Bogaert [7] neglected the diffuse double layer and assumed an ionic monolayer or bilayer at the ITIES formed by the specifically adsorbed ions.
Keywords
- Electrical Double Layer
- Electrolyte Concentration
- Surface Charge Density
- Diffuse Double Layer
- Interfacial Capacitance
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Verwey, E.J.W., Niessen, K.F.: Philos. Mag. 28, 435–446 (1939)
Gouy, G.: C. R. Acad. Sci. 149, 654 (1910)
Chapman, D.L.: Philos. Mag. 25, 475 (1913)
Gavach, G., Seta, P., d’Epenoux, B.: J. Electroanal. Chem. 83, 225–235 (1977)
Krylov, V.S., Myamlin, V.A., Boguslavsky, L.I., Manvelyan, M.A.: Elektrokhimiya 13, 834–840 (1977)
Gugeshashvili, M.I., Manvelyan, M.A., Boguslavsky, L.I.: ibid. 10, 819–822 (1974)
Joos, P., Vanden Bogaert, R.: J. Colloid. Interface Sci. 56, 206–212 (1976)
Kahleweit, M., Strehlow, H.: Z. Elektrochem. 58, 658 (1954)
Boguslavsky, L.I., Frumkin, A.N., Gugeshashvili, M.I.: Elektrokhimiya 12, 856–860 (1976)
Seta, P., d’Epenoux, B., Gavach, C.: J. Electroanal. Chem. 95, 191–199 (1979)
Reid, J.D., Melroy, O.R., Buck, R.P.: ibid. 147, 71–82 (1983)
Girault, H.H., Schiffrin, D.I.: ibid. 150, 43–49 (1983)
Gros, M., Gromb, S., Gavach, C.: ibid. 89, 29–36 (1978)
Kakiuchi, T., Senda, M.: Bull. Chem. Soc. Jpn. 56, 1753–1760 (1983)
Kakiuchi, T., Senda, M.: ibid. 56, 1322–1326 (1983)
Girault, H.H., Schiffrin, D.J.: J. Electroanal. Chem. 170, 127–141 (1984)
Samec, Z., Mareček, V., Homolka, D.: ibid. 126, 121–129 (1981)
Hájková, P., Homolka, D., Mareček, V., Samec, Z.: ibid. 151, 277–282 (1983)
Homolka, D., Hájková, P., Mareček, V., Samec, Z.: ibid. 159, 233–238 (1983)
Mareček, V., Samec, Z.: ibid. 149, 185–192 (1983)
Samec, Z., Mareček, V., Homolka, D.: Faraday Discuss. Chem. Soc. 77, 197–208 (1984)
Reid, J.D., Vanýsek, P., Buck, R.P.: J. Electroanal. Chem. 161, 1–15 (1984)
Reid, J.D., Vanýsek, P., Buck, R.P.: ibid. 170, 109–125 (1984)
Osakai, T., Kakutani, T., Senda, M.: Bull. Chem. Soc. Jpn. 57, 370–376 (1984)
Girault, H.H.J., Schiffrin, D.I.: J. Electroanal. Chem. 161, 415–417 (1984)
Geblewicz, G., Figaszewski, Z., Koczorowski, Z.: ibid. 177, 1–12 (1984)
Le Hung, Q.: ibid. 115, 159–174 (1980)
Kakiuchi, T., Senda, M.: Bull. Chem. Soc. Jpn. 56, 2912–2918 (1983)
Figaszewski, Z.: J. Electroanal. Chem. 139, 309–315 (1982)
Samec, Z., Mareček, V., Weber, J.: ibid. 100, 841–852 (1979)
Mareček, V., Samec, Z.: ibid. 185, 263–271 (1985)
Samec, Z., Mareček, V., Homolka, D.: ibid. 187, 31–51 (1985)
Kakutani, T., Osakai, T., Senda, M.: Bull. Chem. Soc. Jpn. 56, 991–996 (1983)
Melroy, O.R., Bronner, W.E., Buck, R.P.: J. Electrochem. Soc. 130, 373–380 (1983)
Silva, F., Moura, C.: J. Electroanal. Chem. 177, 317–323 (1984)
Berzins, T., Delahay, P.: J. Am. Chem. Soc. 77, 6448–6453 (1955)
Koryta, J., Vanýsek, P., Březina, M.: J. Electroanal. Chem. 75, 211–228 (1977)
Samec, Mareček, V., Holub, K., Hájková, P.: J. Electroanal. Chem. (in press)
Henderson, D., Blum, L., Lozada-Casson, M.: J. Electroanal. Chem. 150, 291–303 (1983)
Henderson, D., Blum, L.: ibid. 111, 217–222 (1980)
Vorotyntsev, M.A.: Kornyshev, A.A.: Elektrokhimiya 20, 3 (1984)
Outhwaite, C.W., Bhuigan, L.B., Levine, S.: J. Chem. Soc. Faraday Trans. II 76, 1388–1408 (1980)
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer-Verlag Berlin, Heidelberg
About this chapter
Cite this chapter
Samec, Z., Mareček, V. (1987). Study of the Electrical Double Layer at the Interface Between Two Immiscible Electrolyte Solutions by Impedance Measurements. In: Kazarinov, V.E. (eds) The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71881-6_7
Download citation
DOI: https://doi.org/10.1007/978-3-642-71881-6_7
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-71883-0
Online ISBN: 978-3-642-71881-6
eBook Packages: Springer Book Archive