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Hopping Charge Carriers in Molecular Crystals and Biopolymers: The Fröhlich Connection

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Abstract

It is possibly the case for all scholars and researchers that the main thrust of their work is consciously, or subconsciously, influenced by a few key papers and books read in their formative years. For me these took the form of two small books (Fröhlich, 1958; Szent-Györgyi, 1960) and one research note (Fröhlich and Sewell, 1959). Szent-Györgyi’s Introduction to a Submolecular Biology deals with the possibility that the phenomena of molecular charge-transfer interactions and electronic mobility might be of relevance for a full understanding of the subtleties of the living state. This fired off my interest in matters biological and directed me towards the interdisciplinary subject matter of biomolecular electronics. However, the basics of the methodologies of this work were derived from the works of Fröhlich.

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References

  • Balanovski, E. and Beaconsfield, P., Solitonlike excitations in biological systems, Phys. Rev. A., 32 (1985) 3059.

    Article  ADS  Google Scholar 

  • Bone, S. and Pethig, R., Temperature dependence of the low frequency dielectric dispersion in the perylene + chloranil complex, J. Chem. Soc., Faraday Trans. I., 74 (1978) 720.

    Article  Google Scholar 

  • Bone, S., Eden, J., Gascoyne, P.R.C. and Pethig, R., Conduction and dielectric polarisation in proteins and molecular complexes, J. Chem. Soc., Faraday Trans. I., 77 (1981) 1729.

    Article  Google Scholar 

  • Carnochan, P. and Pethig, R., Low frequency dielectric dispersions in the Perylene + chloranil charge transfer complex, J. Chem. Soc., Faraday Trans. I, 72 (1976) 2355.

    Article  Google Scholar 

  • Cross, T.E. and Pethig, R., Microwave Hall effect measurements on biopolymers, Int. J. Quantum Chem: Quantum Biol. Symp., 7 (1980) 385.

    Google Scholar 

  • Eden, J., Gascoyne, P.R.C. and Pethig, R., Dielectric and electrical properties of hydrated bovine serum albumin, J. Chem. Soc., Faraday Trans. I, 76 (1980) 426.

    Article  Google Scholar 

  • Eley, D.D. and Pethig, R., Microwave Hall effect measurements on biological materials, Disc. Faraday Soc., 51 (1971) 164.

    Article  Google Scholar 

  • Fröhlich, H., Theory of dielectrics, Clarendon Press, Oxford, 2nd edition, 1958. (1st. Ed. 1949 ).

    MATH  Google Scholar 

  • Fröhlich, H. and Sewell, G.L., Electric conduction in semiconductors, Proc. Phys. Soc., 74 (1959) 643.

    Article  ADS  Google Scholar 

  • Gascoyne, P.R.C., Pethig, R. and Szent-Györgyi, A., Water structure dependent charge transport in proteins, Proc. Natl. Acad. Sci. USA, 78 (1981) 261.

    Article  ADS  Google Scholar 

  • Hayward, D. and Pethig, R., Frequency dependence of the conductivity of molecular solids, Phys. stat. sol. (a), 32 (1975) K177.

    Article  ADS  Google Scholar 

  • Lewis, T.J., The dielectric behaviour of non-crystalline solids., Dielectric and Related Molecular Processes, Chemical Society, London, Vol. 3 (1977) 186.

    Google Scholar 

  • Lewis, T.J. and Pethig, R., The determination of localized energy states in -carotene by a. c. conduction studies, in Excited States of Biological Molecules, Ed. Birks, J.B., Wiley Interscience, London (1976) 342.

    Google Scholar 

  • Morgan, K. and Pethig, R., D.C. Hall current measurements on organic crystals, J. Materials Sci., 6 (1971) 179.

    Article  ADS  Google Scholar 

  • Pethig, R., Dielectric and electronic properties of biological materials, Wiley, Chichester (1979).

    Google Scholar 

  • Pethig, R. and South, R.B., Hall effect measurements at 33 GHz, IEEE Trans. Instrum. Meas., IM-23 (1974) 460.

    Google Scholar 

  • Pope, M. and Swenberg, C.E., Electronic Processes in Organic Crystals, Clarendon Press, Oxford (1982).

    Google Scholar 

  • Rosseinsky, D.R., Stephan, J.A. and Tonge, J.S., Site-transfer electronic conductivity, J. Chem. Soc., Faraday Trans. I., 77 (1981) 1719.

    Article  Google Scholar 

  • Suhai, S., Theoretical investigations of semiconductive properties in proteins. I. Electrical conductivity, charge mobilities, and free paths in polyglycine, Biopolmers, 13 (1974) 1731.

    Article  Google Scholar 

  • Szent-Györgyi, A., Introduction to a Submolecular Biology, Academic Press, New York (1960).

    Google Scholar 

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© 1987 Springer-Verlag Berlin Heidelberg

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Pethig, R. (1987). Hopping Charge Carriers in Molecular Crystals and Biopolymers: The Fröhlich Connection. In: Barrett, T.W., Pohl, H.A. (eds) Energy Transfer Dynamics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71867-0_25

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  • DOI: https://doi.org/10.1007/978-3-642-71867-0_25

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-17502-5

  • Online ISBN: 978-3-642-71867-0

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