Skip to main content
SpringerLink
Log in

Guest-Host Interaction and Photochemical Transformation of Silver Particles Isolated in Rare Gas Matrices

  • Conference paper
Metal Clusters

Abstract

Silver dimers and small clusters isolated in rare gas matrices are studied by UV-VIS absorption, emission, and resonance Raman spectroscopy. One, two, and three dimer trapping sites can be identified in Xe, Kr, and Ar matrices, respectively. The sites are identified by computer simulation to be either ofD 4h symmetry, with the molecules aligned in the <100>-direction of the fcc-host lattice, or of D 2h symmetry, with the molecules occupying single or double vacancies and aligned in the <110>-direction. Low energy external modes of the dimers are observed in the resonance Raman spectra. They probe the guest-host interaction of the molecules and are assigned to librational modes.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Ozin, G. A., Mitchell, S. A.: Angew. Chem. Int. Ed. Engl. 22, 674 (1983)

    Google Scholar 

  2. Weltner, W., Van Zee, R. J.: Annu. Rev. Phys. Chem. 35, 291 (1984)

    Google Scholar 

  3. Gruen, D. M., Bates, J. K.: Inorg. Chem. 16, 2450 (1977)

    Article  Google Scholar 

  4. Schulze, W., Becker, H.-U., Abe, H.: Chem. Phys. 35, 177 (1978); Ber. Bunsenges. Phys. Chem. 82, 138 (1978)

    Article  Google Scholar 

  5. Schulze, W., Becker, H.-U., Minkwitz, R., Manzel, K.: Chem. Phys. Lett. 55, 59 (1978)

    Article  ADS  Google Scholar 

  6. Ozin, G. A., Huber, H.: Inorg. Chem. 17, 155 (1978)

    Article  Google Scholar 

  7. Mitchell, S. A., Ozin, G. A.: J. Am. Chem. Soc. 100, 6776 (1978)

    Article  Google Scholar 

  8. Welker, T., Martin, T. P.: J. Chem. Phys. 70, 5683 (1979)

    Article  ADS  Google Scholar 

  9. Ozin, G. A., Huber, H., Mitchell, S. A.: Inorg. Chem. 18, 2932 (1979)

    Article  Google Scholar 

  10. Leutloff, D., Kolb, D.M.: Phys. Chem. 83, 666 (1979)

    Google Scholar 

  11. Grinter, R., Armstrong, S., Jayasooria, U. A., McCombie, J., Norris, D., Springall, J. P.: Faraday Symp. Chem. Soc. 14, 94 (1980)

    Google Scholar 

  12. Mitchell, S. A., Kenney-Wallace, G. A., Ozin, G. A.: J. Am. Chem. Soc. 103, 6030 (1981)

    Article  Google Scholar 

  13. Howard, J. A., Preston, K. F., Mile, B.: J. Am. Chem. Soc. 103, 6226 (1981)

    Article  Google Scholar 

  14. Mitchell, S. A., Ozin, G. A.: J. Phys. Chem. 88, 1425 (1984)

    Article  Google Scholar 

  15. Bechthold, P. S., Kettler, U., Krasser, W.: Solid State Commun. 52, 347 (1984); Surf. Sci. 156, 875 (1985)

    Google Scholar 

  16. Kettler, U., Bechthold, P. S., Krasser, W.: Surf. Sci. 156, 867 (1985)

    Article  ADS  Google Scholar 

  17. Kernisant, K., Thompson, G. A., Lindsay, D. M.: J. Chem. Phys. 82, 4739 (1985)

    Article  ADS  Google Scholar 

  18. Shim, I., Gingerich, K. A.: J Chem. Phys. 79, 2903 (1983)

    Article  ADS  Google Scholar 

  19. Martins, J. L., Andreoni, W.: Phys. Rev. A28, 3637 (1983)

    Article  ADS  Google Scholar 

  20. Rabii, S., Yang, C. Y.: Chem. Phys. Lett. 105, 480 (1984)

    Article  ADS  Google Scholar 

  21. Flad, J., Igel-Mann, G., Preuss, H., Stoll, H.: Chem. Phys. 90, 257 (1984)

    Article  Google Scholar 

  22. Bäsch, H.: J. Am. Chem. Soc. 103, 4657 (1981)

    Article  Google Scholar 

  23. Andreoni, W., Martins, J. L.: Surf. Sci. 156, 635 (1985); (to be published)

    Google Scholar 

  24. Boudon, J.: Growth and properties of metal clusters. Amster-dam: Elsevier 1980

    Google Scholar 

  25. Otto, A.: In: Light scattering in solids I V: In: Topics in Applied Physics. Cardona, M., Güntherodt, G. (eds.), Vol. 54, p. 289. Berlin, Heidelberg, New York, Tokyo: Springer 1984

    Google Scholar 

  26. Kettler, U.: Ph.D. Thesis, Universität zu Köln, (1984) (Berichte der Kernforschungsanlage Jülich No. 1980 (1985))

    Google Scholar 

  27. Ruamps, J.: Ann. Phys. (Paris) 4, 1111 (1959); Brown, C. M., Ginter, M. L.: J. Mol. Spectrosc. 69, 25 (1978); Srdanov, V. I., Pesic, D. S.: J. Mol. Spectrosc. 90, 27 (1981)

    Google Scholar 

  28. Endoh, Y., Shirane, G., Skalyo J., Jr.: Phys. Rev. B11, 1681 (1975)

    Article  ADS  Google Scholar 

  29. Barker, A. S., Jr., Sievers, A. J.: Rev. Mod. Phys. 47, Suppl. 2, (1975)

    Google Scholar 

  30. Bechthold, P. S., Schober, H. R.: (to be published)

    Google Scholar 

  31. Schober, H. R.: J. Phys. F7, 1127 (1977)

    Article  ADS  Google Scholar 

  32. Telle, H., Telle, U.: Comp. Phys. Comm. 28, 1 (1982)

    Article  ADS  Google Scholar 

  33. Abrahamson, A.A.: Phys. Rev. 178, 76 (1969); see also: Torrens, I.M.: Interatomic potentials, New York: Academic Press 1972

    Google Scholar 

  34. Thompson, G. A., Lindsay, D. M.: J. Chem. Phys. 74, 959 (1981)

    Article  ADS  Google Scholar 

  35. Moskovits, M.: Chem. Phys. Lett. 118, 111 (1985)

    Article  ADS  Google Scholar 

  36. Garland, D. A., Lindsay, D. M.: J. Chem. Phys. 78, 2813 (1983)

    Article  ADS  Google Scholar 

  37. Howard, J. A., Sutcliffe, R., Mile, B.: Chem. Phys. Lett. 112, 84 (1984)

    Article  ADS  Google Scholar 

  38. Thompson, G. A., Tischler, F., Garland, D., Lindsay, D. M.: Surf. Sci. 106, 408 (1981)

    Article  ADS  Google Scholar 

  39. Porto, S. P. S., Krishnan, R. S.: J. Chem. Phys. 47, 1009 (1967)

    Article  ADS  Google Scholar 

Download references

Author information

Author notes

  1. P. S. Bechthold

    Present address: Chemistry Division, Argonne National Laboratory Argonne, Illinois, 60439, USA

  2. U. Kettler

    Present address: Department of Physics, University of California, Santa Barbara, CA, 93 106, USA

Authors and Affiliations

  1. Institut für Festkörperforschung, Kernforschungsanlage Jülich GmbH, Jülich 1, Postfach 1913, D-5170, Federal Republic of Germany

    P. S. Bechthold, U. Kettler, H. R. Schober & W. Krasser

Authors
  1. P. S. Bechthold
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. U. Kettler
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. R. Schober
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. W. Krasser
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Physikalisches Institut, Universität Heidelberg, Philosophenweg 12, D-6900, Heidelberg, Germany

    Frank Träger  & Gisbert zu Putlitz  & 

Rights and permissions

Reprints and permissions

Copyright information

© 1986 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Bechthold, P.S., Kettler, U., Schober, H.R., Krasser, W. (1986). Guest-Host Interaction and Photochemical Transformation of Silver Particles Isolated in Rare Gas Matrices. In: Träger, F., zu Putlitz, G. (eds) Metal Clusters. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71571-6_23

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-71571-6_23

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-71573-0

  • Online ISBN: 978-3-642-71571-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation