Natural Product Synthesis Via Functionally Substituted Vinyl Carbanions

  • Richard R. Schmidt
Conference paper

Summary

Direct C-lithiation of functionally substituted acrylates yields short routes for the synthesis of butenolides, tetronates, α-hydroxybutenolides, and α-hydroxytetronates. Approaches to the synthesis of aspertetronins, gregatins, ascorbic acids, chiorothricolide, and 3-deoxy-D-manno-2-octulosonate (KDO) are discussed

Keywords

Boron Aldehyde Pyruvate MeOH Acrylate 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1986

Authors and Affiliations

  • Richard R. Schmidt
    • 1
  1. 1.Fakultät ChemieUniversität KonstanzKonstanzGermany

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