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Partial Molar Volumes of Biochemical Model Compounds in Aqueous Solution

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Thermodynamic Data for Biochemistry and Biotechnology

Abstract

Partial molar volumes have proved very useful in the study of molecular and ionic interactions in solution. The values at infinite dilution provide information about solute-solvent interactions and the concentration dependence will reflect solute-solute interactions. The present review is aimed at volumes of relatively simple organic molecules that may be looked upon as biochemical model compounds. It is believed that the partial molar volumes of these compounds in water represent a basis for the understanding of complex biochemical systems. With this in mind, it is especially interesting to examine homologous series. Systematic trends, such as additivity relations, are of special importance and will be discussed at the end.

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Abbreviations

V:

volume of the solution [dm3 mol-1]

V *1 :

molar volume of the pure solvent [cm3 mol- 1]

V2 :

partial molar volume of solute [Cm3 mol-1] in a two-component system

V x0 :

partial molar volume of solute x at infinite dilution [cm3 mol-1]

V 0NaA :

partial molar volumes of sodium carboxylates at infinite dilution [cm3 mol- 1]

V 0HA :

partial molar volumes of carboxylic acids [cm3 mol- 1] at infinite dilution

Vφ :

apparent molar volume [cm3 mol-1]

Vφx :

apparent molar volume of substance x [cm3 mol- 1]

VφBHO :

apparent molar volume of a hypothetical neutral aquoamine complex, BH20, that cn dissociate into the hydrolysis products BH+ and OH−

VW :

vander Waals volume

rW :

van der Waals radius

∆Vo :

change in molar volume

ρ* :

density of solvent [gcm-3]

ρ:

density of solute [gcm-3]

M2 :

molar mass of solute

m:

molality of solute [mol solute/1000 g solvent]

α:

degree of hydrolysis

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Authors
  1. Harald Høiland
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  1. Institut für Biophysik und Physikalische Biochemie, Universität Regensburg, Universitätsstraße 31, 8400, Regensburg, Germany

    Hans-Jürgen Hinz

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Høiland, H. (1986). Partial Molar Volumes of Biochemical Model Compounds in Aqueous Solution. In: Hinz, HJ. (eds) Thermodynamic Data for Biochemistry and Biotechnology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71114-5_2

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