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Gas-Liquid and Solid-Liquid Phase Equilibria in Binary Aqueous Systems of Nonelectrolytes

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Thermodynamic Data for Biochemistry and Biotechnology

Abstract

Solubility data of nonelectrolytes in water are very useful in many fields from engineering to biology, but until recently critical collections of such data, in summarizing tables, have been neglected. Only in the last few years has the situation noticeably improved, and some excellent reviews containing critical and exhaustive tables on the solubility of gases in water [1] and other solvents [2] have been published. Additionally, a fundamental project has been set up by the IUPAC, Solubility Data Series (Pergamon Press/A. S. Kertes), which plans to collect and critically evaluate all existing solubility data covering physical and biological systems. One hundred volumes were planned for publication between 1979 and 1989. By the end of 1982, 17 volumes of the series had already appeared. Eleven of these (from 360 to 650 pages) contain solubility data for gases such as noble gases, hydrogen, nitrogen, oxygen, ozone, oxides of nitrogen, oxides of sulfur, ethane and hydrogen halides in water and nonaqueous solvents. The other six books deal with solubility data of liquid and solid substances. Among the nonelectrolytes, solubility data of alcohols and hydrocarbons in water, and of halogenated benzenes, toluenes, xylenes, and phenols in various solvents have been studied.

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Abbreviations

α:

Bunsen coefficient (see Table 1)

L:

Ostwald coefficient (see Table 1)

L*:

Ostwald coefficient extrapolated to c→O

S:

Kuenen coefficient (see Table 1)

kH :

Henry’s law constant (see Table 1)

So :

weight solubility (see Table 1)

x:

mole fraction of solute

∆G *b :

standard Gibbs energy change for the transfer of one mole of gas from 1 molar ideal state to ideal aqueous solution of 1 molar concentration

∆G 0h :

standard Gibbs energy change for the transfer of one mole of gas from ideal state (1atm partial pressure) to (hypothetical) ideal aqueous solution of unit mole fraction at 298K

∆H h0 :

standard enthalpy change for the same process

∆S h0 :

standard entropy change for the same process

∆C p0 :

standard heat capacity change for the same process

∆Hs :

molar enthalpies of solution

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Authors
  1. Sergio Cabani
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  2. Paolo Gianni
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Editors and Affiliations

  1. Institut für Biophysik und Physikalische Biochemie, Universität Regensburg, Universitätsstraße 31, 8400, Regensburg, Germany

    Hans-Jürgen Hinz

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Cabani, S., Gianni, P. (1986). Gas-Liquid and Solid-Liquid Phase Equilibria in Binary Aqueous Systems of Nonelectrolytes. In: Hinz, HJ. (eds) Thermodynamic Data for Biochemistry and Biotechnology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-71114-5_10

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  • DOI: https://doi.org/10.1007/978-3-642-71114-5_10

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