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Geology and Metallogeny of Copper Deposits pp 25–42Cite as

Application of Stable Isotopic Studies to Problems of Magmatic Sulfide Ore Genesis With Special Reference to the Duluth Complex, Minnesota

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Part of the book series: Special Publication No. 4 of the Society for Geology Applied to Mineral Deposits ((MINERAL DEPOS.,volume 4))

Abstract

Analyses of the isotopic composition of S, C, O, and H in mafic igneous rocks may provide valuable information regarding the extent of contamination by continental crust material. Partial melting and devolatilization of country rocks are important processes in the generation of many Cu—Ni deposits associated with mafic igneous rocks. Sulfur isotopes provide a means of evaluating the possibility of extraneous sulfur addition to a melt. Variability and distribution of δ 34S values may also provide data relating to the timing and mechanisms of sulfur production and incorporation into the melt. Oxygen, hydrogen, and carbon isotopes also can be sensitive indicators of isotopic contamination, whether by partial melting, devolatilization, or solid state exchange. Zones of contamination within an igneous sequence are likely to be areas where factors that control sulfide solubility (T, fS2, fO2, melt composition) have been perturbed, and are thus key sites for ore generation.

Stable isotopic studies of two deposits within the Duluth Complex have high-lighted the importance of country rock contamination in the generation of Cu—Ni ores. For the Dunka-Road deposit devolatilization of country rocks has resulted in essentially in situ contamination, and the formation of ore that is variable in both its spatial distribution and δ 34S values. Partial melting and major element contamination are restricted to areas near the margins of xenoliths. At the Babbitt deposit, contamination via both partial melting and devolatilization has been significant. Sulfur isotopic distribution between igneous and metasedimentary rocks suggests that sulfur must have been derived prior to or during magma ascent. Partial melting of country rocks and oxygen isotopic exchange may have occurred either before or after magma emplacement. Chemical diffusion, as well as fluid dynamic properties of mixing are thought to control the isotopic inhomogeneity that characterizes sulfide ore zones in the Duluth Complex.

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Authors and Affiliations

  1. Geology Department, Indiana University, Bloomington, IN, 47405, USA

    E. M. Ripley

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  1. E. M. Ripley
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Editors and Affiliations

  1. Institut für Mineralogie und Lagerstättenlehre, RWTH Aachen, Wüllnerstraße 2, 5100, Aachen, Germany

    Günther H. Friedrich

  2. CCCP/IGEM, Staromonetny, 35, 109017, Moscow, USSR

    Alexandr D. Genkin

  3. Department of Geology, University of Toronto, M5S 1A1, Toronto, Ontario, Canada

    Anthony J. Naldrett

  4. 1402 NW 18th Street, 32605, Gainesville, FL, USA

    John D. Ridge

  5. 8 West Hill Park, N6 6ND, Highgate Village London, England

    Richard H. Sillitoe

  6. Geologisk Institut Norges Tekniske Høgskole, Universitetet i Trondheim, 7034, Trondheim, Norway

    Frank M. Vokes

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© 1986 Springer-Verlag Berlin Heidelberg

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Ripley, E.M. (1986). Application of Stable Isotopic Studies to Problems of Magmatic Sulfide Ore Genesis With Special Reference to the Duluth Complex, Minnesota. In: Friedrich, G.H., Genkin, A.D., Naldrett, A.J., Ridge, J.D., Sillitoe, R.H., Vokes, F.M. (eds) Geology and Metallogeny of Copper Deposits. Special Publication No. 4 of the Society for Geology Applied to Mineral Deposits, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-70902-9_3

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  • DOI: https://doi.org/10.1007/978-3-642-70902-9_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-70904-3

  • Online ISBN: 978-3-642-70902-9

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